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Which of the following does not give hal...

Which of the following does not give haloform reaction:

A

`underset(Cl)underset(|)(CH_(2))-underset(O)underset(||)(C)-CH_(3)`

B

`underset(Br)underset(|)(C)H-underset(O)underset(||)(C)-CH_(3)`

C

`underset(Cl)underset(|)(CH_(2))-overset(O)overset(||)(C)-CH_(3)`

D

`Ph-underset(O)underset(||)(C)-Ph`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given compounds does not give a haloform reaction, we need to understand the conditions required for a compound to undergo this reaction. ### Step-by-Step Solution: 1. **Understand the Haloform Reaction**: The haloform reaction occurs with compounds that contain the acetyl group (CH3CO-) or similar structures. Specifically, the compound must have a methyl ketone (RCOCH3) or a compound that can be oxidized to a methyl ketone. 2. **Identify the Required Functional Group**: The key functional group for the haloform reaction is the presence of the acetyl group (CH3CO-). This means that for a compound to undergo the haloform reaction, it should have a structure that can be represented as RCOCH3. 3. **Analyze the Given Options**: We need to look at each option provided in the question to see if they contain the required acetyl group. - **Option A**: COCH3 (This is a methyl ketone and will undergo the haloform reaction.) - **Option B**: COCH3 (This is also a methyl ketone and will undergo the haloform reaction.) - **Option C**: COCH3 (This is again a methyl ketone and will undergo the haloform reaction.) - **Option D**: CH3=O CH (This compound has a structure that does not contain the required CH3CO- group. It has two benzene rings and does not fit the criteria for the haloform reaction.) 4. **Conclusion**: Since options A, B, and C all contain the necessary acetyl group (CH3CO-), they will undergo the haloform reaction. However, option D does not contain this group and therefore will not undergo the haloform reaction. ### Final Answer: The correct answer is **Option D**, as it does not give a haloform reaction. ---

To determine which of the given compounds does not give a haloform reaction, we need to understand the conditions required for a compound to undergo this reaction. ### Step-by-Step Solution: 1. **Understand the Haloform Reaction**: The haloform reaction occurs with compounds that contain the acetyl group (CH3CO-) or similar structures. Specifically, the compound must have a methyl ketone (RCOCH3) or a compound that can be oxidized to a methyl ketone. 2. **Identify the Required Functional Group**: ...
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RESONANCE ENGLISH-CARBONYL COMPOUNDS (ALDEHYDES & KETONES ) & CARBOXYLIC ACID -Part-I
  1. What is the final products (B) of this reaction sequences ?

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  2. Cannizzaro reaction does not take place with

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  3. Which of the following does not give haloform reaction:

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  4. Synthesis of an ester involves the reaction of alcohols with

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  5. When phenyl magnesium bromide reacts with t-butanol the product would ...

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  6. Products A of the above reactions is

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  7. In the reaction sequence CH(3)-overset(O)overset(||)(C)-H-underset(...

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  8. on reductive ozonolysis yeilds

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  9. A cyanohydrin of a compound X on hydrolysis gives lactic acid. The X i...

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  10. Which of the following will not undergo aldol condensation?

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  11. PhCHO +(CH(3)CO)(2)O overset((1)CH(3)COONa)underset((2)"hydrolysis", D...

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  12. What will be the product of the following reaction Ph-underset(Me)un...

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  13. In the following conversion Which of the following reagents is su...

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  14. The major products formed in the reaction C(6)H(5)CHO+CH(3)NO(2) ove...

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  15. For the following acids the rate of decarboxylation on heating would b...

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  16. R-overset(O)overset(||)(C)-Cl overset(NH(3))toNH(4)Cl+(X) overset(P(4)...

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  17. Which element in group 15 does not show allotropy .

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  18. Starting from propanoic acid, the following reactions were carried out...

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  19. Which of the following acid remains unaffected on heating ?

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  20. m-Chlorobenzaldehyde on reaction with concentrated KOH at room temera...

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