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In the reaction sequence CH(3)-overse...

In the reaction sequence
`CH_(3)-overset(O)overset(||)(C)-H-underset(.^(Θ)OH)overset(HCN)rarr(A) underset(Delta)overset(H_(2)O //overset(o+)(H))rarr` Product is/are :

A

Diasteromers

B

Racemic mixture of hydroxy acid

C

Product is racemic mixture of cyanohydrin

D

Products is optically inactive

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The correct Answer is:
To solve the given question, we will follow the reaction sequence step by step. ### Step 1: Identify the Reactants The reactant given is acetaldehyde (CH₃CHO) and it is reacted with HCN in a basic medium. ### Step 2: Understand the Reaction Type The reaction between acetaldehyde and HCN is an example of a nucleophilic addition reaction. In this reaction, the nucleophile (CN⁻) attacks the electrophilic carbon of the carbonyl group. ### Step 3: Mechanism of the Reaction 1. The carbonyl carbon (C=O) is electrophilic due to the partial positive charge on it. The nucleophile (CN⁻) attacks this carbon. 2. The oxygen atom of the carbonyl group becomes negatively charged as a result of the nucleophilic attack. 3. The intermediate formed is a cyanohydrin, which has the structure: \[ \text{C(OH)(CH₃)(CN)} \] This is referred to as product A. ### Step 4: Hydrolysis of Cyanohydrin The cyanohydrin undergoes hydrolysis when treated with water (H₂O) and heat. The hydrolysis reaction can be represented as follows: 1. The cyanohydrin reacts with water, leading to the formation of a hydroxy acid. 2. The product formed after hydrolysis is lactic acid (C₃H₆O₃), which can be represented as: \[ \text{CH₃CHOHCOOH} \] ### Step 5: Determine the Optical Activity Lactic acid exists in two forms: L-lactic acid and D-lactic acid, which are enantiomers (non-superimposable mirror images). Since both forms are produced in equal amounts during the reaction, the final product is a racemic mixture. ### Conclusion The final product of the reaction sequence is a racemic mixture of lactic acid. ### Answer The correct answer is: **A racemic mixture of lactic acid.** ---

To solve the given question, we will follow the reaction sequence step by step. ### Step 1: Identify the Reactants The reactant given is acetaldehyde (CH₃CHO) and it is reacted with HCN in a basic medium. ### Step 2: Understand the Reaction Type The reaction between acetaldehyde and HCN is an example of a nucleophilic addition reaction. In this reaction, the nucleophile (CN⁻) attacks the electrophilic carbon of the carbonyl group. ...
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RESONANCE ENGLISH-CARBONYL COMPOUNDS (ALDEHYDES & KETONES ) & CARBOXYLIC ACID -Part-I
  1. Which of the following does not give haloform reaction:

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  2. Synthesis of an ester involves the reaction of alcohols with

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  3. When phenyl magnesium bromide reacts with t-butanol the product would ...

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  4. Products A of the above reactions is

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  5. In the reaction sequence CH(3)-overset(O)overset(||)(C)-H-underset(...

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  6. on reductive ozonolysis yeilds

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  7. A cyanohydrin of a compound X on hydrolysis gives lactic acid. The X i...

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  8. Which of the following will not undergo aldol condensation?

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  9. PhCHO +(CH(3)CO)(2)O overset((1)CH(3)COONa)underset((2)"hydrolysis", D...

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  10. What will be the product of the following reaction Ph-underset(Me)un...

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  11. In the following conversion Which of the following reagents is su...

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  12. The major products formed in the reaction C(6)H(5)CHO+CH(3)NO(2) ove...

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  13. For the following acids the rate of decarboxylation on heating would b...

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  14. R-overset(O)overset(||)(C)-Cl overset(NH(3))toNH(4)Cl+(X) overset(P(4)...

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  15. Which element in group 15 does not show allotropy .

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  16. Starting from propanoic acid, the following reactions were carried out...

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  17. Which of the following acid remains unaffected on heating ?

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  18. m-Chlorobenzaldehyde on reaction with concentrated KOH at room temera...

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  19. The given reaction is known as :

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  20. In which of the following reactions benzaldehyde is the final major pr...

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