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The major products formed in the reactio...

The major products formed in the reaction
`C_(6)H_(5)CHO+CH_(3)NO_(2) overset(NaOH)underset("Heat")to(X)`

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To solve the reaction between benzaldehyde (C₆H₅CHO) and nitromethane (CH₃NO₂) in the presence of sodium hydroxide (NaOH) and heat, we can follow these steps: ### Step 1: Identify the Reactants The reactants in this reaction are: - Benzaldehyde (C₆H₅CHO) - Nitromethane (CH₃NO₂) ### Step 2: Understand the Role of the Base Sodium hydroxide (NaOH) acts as a base in this reaction. It will deprotonate the nitromethane, leading to the formation of a nucleophile. The hydrogen atom from the methyl group (CH₃) of nitromethane is abstracted by the hydroxide ion (OH⁻). ### Step 3: Formation of the Nucleophile When NaOH abstracts a proton from nitromethane, it forms a carbanion: - CH₃NO₂ → CH₂NO₂⁻ (carbanion) ### Step 4: Nucleophilic Attack The carbanion (CH₂NO₂⁻) acts as a nucleophile and attacks the electrophilic carbon of the carbonyl group in benzaldehyde (C₆H₅CHO). The carbonyl carbon is electrophilic due to the electron-withdrawing nature of the oxygen atom. ### Step 5: Formation of the Intermediate The nucleophilic attack results in the formation of an intermediate: - C₆H₅C(OH)(CH₂NO₂) (this is a tetrahedral intermediate) ### Step 6: Elimination of Water Upon heating, the intermediate undergoes dehydration (loss of water). The hydroxyl group (OH) from the intermediate and a hydrogen from the methylene group (CH₂) are eliminated, leading to the formation of an alkene. ### Step 7: Final Product The final product of the reaction is: - C₆H₅CH=CHNO₂ (Benzene with a double bond to a carbon that is attached to a nitro group) ### Conclusion The major product formed in the reaction of benzaldehyde with nitromethane in the presence of NaOH and heat is: - C₆H₅CH=CHNO₂

To solve the reaction between benzaldehyde (C₆H₅CHO) and nitromethane (CH₃NO₂) in the presence of sodium hydroxide (NaOH) and heat, we can follow these steps: ### Step 1: Identify the Reactants The reactants in this reaction are: - Benzaldehyde (C₆H₅CHO) - Nitromethane (CH₃NO₂) ### Step 2: Understand the Role of the Base ...
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RESONANCE ENGLISH-CARBONYL COMPOUNDS (ALDEHYDES & KETONES ) & CARBOXYLIC ACID -Part-I
  1. Which of the following does not give haloform reaction:

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  2. Synthesis of an ester involves the reaction of alcohols with

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  3. When phenyl magnesium bromide reacts with t-butanol the product would ...

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  4. Products A of the above reactions is

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  5. In the reaction sequence CH(3)-overset(O)overset(||)(C)-H-underset(...

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  6. on reductive ozonolysis yeilds

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  7. A cyanohydrin of a compound X on hydrolysis gives lactic acid. The X i...

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  8. Which of the following will not undergo aldol condensation?

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  9. PhCHO +(CH(3)CO)(2)O overset((1)CH(3)COONa)underset((2)"hydrolysis", D...

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  10. What will be the product of the following reaction Ph-underset(Me)un...

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  11. In the following conversion Which of the following reagents is su...

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  12. The major products formed in the reaction C(6)H(5)CHO+CH(3)NO(2) ove...

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  13. For the following acids the rate of decarboxylation on heating would b...

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  14. R-overset(O)overset(||)(C)-Cl overset(NH(3))toNH(4)Cl+(X) overset(P(4)...

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  15. Which element in group 15 does not show allotropy .

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  16. Starting from propanoic acid, the following reactions were carried out...

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  17. Which of the following acid remains unaffected on heating ?

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  18. m-Chlorobenzaldehyde on reaction with concentrated KOH at room temera...

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  19. The given reaction is known as :

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  20. In which of the following reactions benzaldehyde is the final major pr...

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