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When acetone is treated with excess of b...

When acetone is treated with excess of bezaldehyde in the presence of base, the crossed condensation add two equivalents of benzaldehyde and expets two equivalent of water and forms [x]. Identify the structure of [X] when [X] reacts with `NH_(2)OH` how many stereoisomers are formed .

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To solve the problem step by step, we will identify the structure of compound [X] formed from the reaction of acetone and benzaldehyde, and then determine how many stereoisomers are produced when [X] reacts with hydroxylamine (NH₂OH). ### Step 1: Write the Reaction When acetone (CH₃COCH₃) is treated with excess benzaldehyde (C₆H₅CHO) in the presence of a base, a crossed aldol condensation occurs. The reaction can be represented as follows: \[ \text{Acetone} + \text{Benzaldehyde} \xrightarrow{\text{Base}} [X] + \text{2 H}_2\text{O} \] ### Step 2: Identify the Structure of [X] In the reaction, benzaldehyde is in excess, which means it will react with both carbonyl groups of acetone. The product [X] can be derived from the aldol condensation of acetone and benzaldehyde. The structure of [X] can be drawn as follows: 1. **Condensation of Acetone and Benzaldehyde**: - The first step involves the formation of a β-hydroxy ketone. - The second step involves dehydration to form an α,β-unsaturated carbonyl compound. The structure of [X] can be represented as: \[ \text{Ph-CH=CH-C(=O)-CH(Ph)-CH}_3 \] Where "Ph" denotes the phenyl group (C₆H₅). ### Step 3: React [X] with NH₂OH When [X] reacts with hydroxylamine (NH₂OH), it forms oxime derivatives. The reaction can lead to the formation of stereoisomers due to the presence of double bonds in the structure of [X]. ### Step 4: Determine the Number of Stereoisomers The compound [X] has two double bonds, which can give rise to geometrical (cis/trans) isomerism. 1. **Identify Double Bonds**: - The double bonds in [X] allow for cis and trans configurations. 2. **Count Possible Configurations**: - For each double bond, there are two configurations (cis and trans). - Since there are two double bonds, the total number of stereoisomers can be calculated as \(2^n\), where \(n\) is the number of double bonds that can exhibit geometrical isomerism. Thus, for [X], the number of stereoisomers is: \[ 2^2 = 4 \text{ stereoisomers} \] ### Final Answer The structure of [X] is an α,β-unsaturated carbonyl compound formed from the reaction of acetone and benzaldehyde. When [X] reacts with hydroxylamine, it produces **4 stereoisomers**.

To solve the problem step by step, we will identify the structure of compound [X] formed from the reaction of acetone and benzaldehyde, and then determine how many stereoisomers are produced when [X] reacts with hydroxylamine (NH₂OH). ### Step 1: Write the Reaction When acetone (CH₃COCH₃) is treated with excess benzaldehyde (C₆H₅CHO) in the presence of a base, a crossed aldol condensation occurs. The reaction can be represented as follows: \[ \text{Acetone} + \text{Benzaldehyde} \xrightarrow{\text{Base}} [X] + \text{2 H}_2\text{O} \] ### Step 2: Identify the Structure of [X] ...
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RESONANCE ENGLISH-CARBONYL COMPOUNDS (ALDEHYDES & KETONES ) & CARBOXYLIC ACID -Part -III
  1. When semicarbazide reacts with a ketone (or aldehyde) to form semicarb...

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  2. Arrange the following compounds in decreasing ordres of K(eq) for hydr...

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  3. When acetone is treated with excess of bezaldehyde in the presence of ...

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  4. Write the components which on claisen condensation could be used to pr...

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  5. Predict the product for each of the following reactions.

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  6. Products is

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  7. Write the product of following reactions :

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  8. A compound 'A' when treated with HNO(3) (in presence of H(2)SO(4) ) gi...

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  9. A+B, Find A and B

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  10. C(6)H(12)O(2)(X) overset(H(3)O^(+))toC(2)H(5)CO(2)H+C(3)H(7)OH, X is

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  11. In the given reaction the products is : CH(3)-CH(2)-underset(O)under...

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  12. Product of following reactions is

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  13. 2-Methychlcyclohexanone is allowed to react with matachloroperbenzoic ...

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  14. Which optically active compound on reduction with LiAlH(4) will give o...

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  15. The reaction,RCOOR'+R''OH (excess) overset(H^(+)or OH^(-))to RCOOR''+R...

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  17. Match the product of column -II with the reaction given in column -I

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  18. How many compounds out of the following are more reactive than ethyl a...

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  19. The product of the following reactions is optically inactive and exist...

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  20. Ph-overset(O)overset(||)(C)-CH(3)+underset("(excess)")(CH(2)=O) overse...

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