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2-Methychlcyclohexanone is allowed to re...

2-Methychlcyclohexanone is allowed to react with matachloroperbenzoic acid. The major product in the reaction is

A

B

C

D

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The correct Answer is:
To solve the question regarding the reaction of 2-methylcyclohexanone with meta-chloroperbenzoic acid, we will follow these steps: ### Step 1: Understand the Reactants - **2-Methylcyclohexanone**: This compound has a cyclohexane ring with a ketone (C=O) functional group at the second carbon and a methyl (CH₃) group at the same position. - **Meta-chloroperbenzoic acid (m-CPBA)**: This is a peracid that can introduce an oxygen atom into the carbon skeleton through an epoxidation reaction. **Hint**: Identify the structure of both reactants to visualize the reaction mechanism. ### Step 2: Reaction Mechanism - The reaction involves the nucleophilic attack of the carbonyl oxygen of 2-methylcyclohexanone on the electrophilic oxygen of m-CPBA. - The oxygen in the peracid will act as an electrophile, and the carbonyl oxygen will act as a nucleophile. **Hint**: Remember that nucleophiles donate electrons to electrophiles in a reaction. ### Step 3: Formation of the Epoxide - Upon the reaction, an epoxide is formed. The oxygen from m-CPBA will form a three-membered cyclic ether with the carbonyl carbon of 2-methylcyclohexanone. - This results in the formation of an intermediate with a cyclic structure. **Hint**: Look for the formation of a three-membered ring (epoxide) in the product. ### Step 4: Ring Opening - The epoxide can undergo ring-opening in the presence of acid or water, leading to the formation of a hydroxyl group (-OH) on one of the carbons of the original ketone. - The other carbon will retain the original substituents, including the methyl group. **Hint**: Consider how the epoxide can be opened and what functional groups will remain in the final product. ### Step 5: Identify the Major Product - After the ring-opening, the major product will be a 7-membered ring compound with a hydroxyl group and the original methyl group retained. - The final structure can be named as 7-methyl-oxepan-2-one. **Hint**: Ensure to check the final structure for the correct number of carbons and functional groups. ### Conclusion The major product formed from the reaction of 2-methylcyclohexanone with meta-chloroperbenzoic acid is **7-methyl-oxepan-2-one**. Therefore, the correct option is **C**.

To solve the question regarding the reaction of 2-methylcyclohexanone with meta-chloroperbenzoic acid, we will follow these steps: ### Step 1: Understand the Reactants - **2-Methylcyclohexanone**: This compound has a cyclohexane ring with a ketone (C=O) functional group at the second carbon and a methyl (CH₃) group at the same position. - **Meta-chloroperbenzoic acid (m-CPBA)**: This is a peracid that can introduce an oxygen atom into the carbon skeleton through an epoxidation reaction. **Hint**: Identify the structure of both reactants to visualize the reaction mechanism. ...
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    B
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  • major product of the reaction is :

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