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Why are low spin tetrahedral complexes n...

Why are low spin tetrahedral complexes not formed?

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Explain the following. Low spin octahedral complexes of nickel are not known.

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Square planar complexes of MX_(2)L_(2) type with coordination number of 4 exhibit geometrical isomerism whereas tetrahedral complexes with similar composition do not. Why? Justify the formation of a low spin complex and a high spin complex taking the examples of [Fe(CN)_(6)]^(3-) and [FeF_(6)]^(3-) on the bases of "crystal field splitting energy". (Delta_(0))

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MODERN PUBLICATION-TEST PAPER 5-EXERCISE
  1. Why does NO(2) dimerises.

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  2. Can Lanthanum ion (Z= 57) exist in +4 oxidation state ? Justify your a...

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  3. Why are low spin tetrahedral complexes not formed?

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  4. Could a co-polymer be formed by step growth or chain growth or both ?

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  5. What is "Chelate effect " ? Explain with examples .

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  6. Oxygen is gas but sulphur is solid because:

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  7. Explain pseudofirst Order reaction with an example .

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  8. What happens when ammonia gas is passed through copper sulphate soluti...

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  9. What happens when acetaldehyde and acetone are separately treated wit...

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  10. Why is NH(2) group of aniline acetylated before carrying out nitration...

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  11. What happens when formaldehyde reacts with ammonia ?

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  12. Match the following columns

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  13. Explain the Hofnann bromamide reaction with one example.

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  14. Low level of noradrenaline is the cause of depression. What type of dr...

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  15. Write notes on band theory of metals.

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  16. What is meant by abnormal molecular mass of solute?

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  17. Activation energy of a reaction is:

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  18. Write short note on Law of independent migration of ions.

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  19. Derive an expression for the rate constant of a first order reaction? ...

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  20. Discuss important of coordination compounds in boiligical system.

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