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Zn^(2+)(aq) + 2e to Zn(s) E°(Zn^(2+)/Zn)...

`Zn^(2+)(aq) + 2e to Zn(s)` `E°(Zn^(2+)`/`Zn)` = - 0.76V, `Ni^(2+)(aq) + 2e to Ni(s)` `E°(Ni^(2+)`/ `Ni)` = - 0.25V, E°cell = _____

A

0.51V

B

-0.51V

C

1.01V

D

none

Text Solution

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The correct Answer is:
A
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Find the stability constant of the complex [ Zn ( NH_(3))_(4)]^(2+) formed in the reaction, Zn^(2+) + 4NH_(3) hArr [ Zn ( NH_(3))_(4)]^(2+) Given that , E_(Zn^(2+) //Zn)^(@) = - 0.76 V and E_([Zn(NH_(3))_(4)]^(2+)//Zn,4NH_(3))^(@) = - 1.03 V

Consider the standard potential of the following cells, (i) Mg^(2+) +2e rarr Mg,E^@=-2.37V (ii) Zn^(2+) + 2erarrZn,E^@ =-0.76V (iii) Ni^(2+) +2e rarrNi,E^@=-0.25V (iv) Fe^(3+) + 3e rarrFe, E_0=-0.04 V find the strongest reducing agent :

MODERN PUBLICATION-ELECTROCHEMISTRY-EXERCISE
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