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C(3)H(9)N cannot represent :...

`C_(3)H_(9)N` cannot represent :

A

(a) 1° amine

B

(b) 2° amine

C

(c) 3° amine

D

(d) quaternary salt

Text Solution

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The correct Answer is:
D
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Answer the following questions The compound of A(C_(3)H_(9)N) reacts with benzene sulphonyl chloride to give a solid insoluble in alkali. Identify 'A'

Write the structure formulae of all the isomeric amines with molecular formula C_(3)H_(9)N and classify them. Why dimethyl amine is more basic than methyl amine?

An organic compound A having molecular formula C_(2)H_(5)O_(2)N on treatment with HNO_(2) gives a blue coloured compound B having molecular formula C_(2)H_(4)O_(3)N_(2) . On reduction, A gives a compound C having molecular formula C_(2)H_(7)N . C on treatment with nitrous acid gives D which gives positive iodoform test. Identify the compounds A, B, C and D.

Draw the structures of different isomers corresponding to the molecular formula C_(3)H_(9)N . Write the IUPAC names of the isomers which will liberate nitrogen gas on treatment with nitrous acid.

A compound A of molecular formula C_(3)H_(7)O_(2)N on reaction with iron and concentrated HCl gives a compound B of molecular formula C_(3)H_(9)N . Compound B on treatment with NaNO_(2) and HCl gives another compound C of molecular formula C_(3)H_(8)O . Compound C gives effervescence with sodium. On oxidation with CrO_(3) , compound C gives a saturated aldehyde containing three carbon atoms. Deduce the structures of compounds A, B and C and write the equations of the reactions involved.

Complete the following equations. (i) C_(6)H_(5)N_(2)Cl + H_(2)O overset(Delta) to (ii) C_(6)H_(5)N_(2)Cl overset(CuCl) underset(HCl) to (iii) C_(6)H_(5)OH overset(ArN_(2)^(+)Cl^(-))underset(OH^(-)) to

MODERN PUBLICATION-ORGANIC COMPOUNDS CONTAINING NITROGEN-EXERCISE
  1. When methyl amine is treated with HNO(2) product obtained is

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  2. Which of the following has highest boiling point ?

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  3. C(3)H(9)N cannot represent :

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  4. Reaction of ethylamine with chloroform in alcoholic KOH gives :

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  5. Out of the following compounds, which is the most basic ?

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  6. An isocyanide on reduction with hydrogrn in the presence of Pt gives :

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  7. Nucleophilic substitution reaction is easier in :

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  8. Secondary nitro alkanes react with nitrous acid to give :

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  9. Nitromethane reacts with benzaldehyde in presence of alc. KOH to form:

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  10. Write the reaction between XeF4 and KI?

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  11. write one use of XeF6

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  12. When methyl iodide reacts with potassium nitrite, the major product ob...

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  13. 2-Nitropropane with boiling HCl gives :

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  14. The reaction of nitrite ion with alkyl halide is a

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  15. 1° Nitroalkane with boiling HCl gives

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  16. Reduction of nitroalkane in neutral medium is made with

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  17. The reaction of acetamide with bromine and caustic potash or NaOBr giv...

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  18. Ethylamine reacts with nitrous acid to form

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  19. Which of the following intermediate does not exist during Hofmann degr...

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  20. The compound C(5)H(13)N is optically active and reacts with HONO to gi...

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