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Two complexes [Cr(H(2)O(6))(6)]Cl(3) and...

Two complexes `[Cr(H_(2)O_(6))_(6)]Cl_(3)` and `[Cr(NH_(3))_(6)]Cl_(3)` (B) are violet and yellow coloured, respectively. The incorrect statement regarding them is :

A

1.both are paragenetic with three unpaired electrons

B

2.`Delta_(0)` value for (A) is less than that of (B)

C

3.`Delta_(0)` values of (A) and (B) are calculated from the energies of violet and yellow light, respectively

D

4.both absorb energies corresponding to their complementary colors

Text Solution

Verified by Experts

The correct Answer is:
C

Both the complexes contain Cr in +3 O.S so they are both paramagnetic with 3 unpaired electrons each. `-H_(2)O` is a weak field ligand and as compared to `NH_(3)` so `Delta_(0)` for A is less than B.
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