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The increasing order of the pKa values o...

The increasing order of the pKa values of the following compounds is:

A

1.B < C < D < A

B

2.C < B < A < D

C

3.NOT IN OPTION

D

4.B < C < A < D

Text Solution

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The correct Answer is:
D

More the acidic strength, lesser will be the value of `pK_(a)`
is most acidic as it’s conjugate base is resonance stabilized by `NO_(2)` group
Overall order of acidic strength

Order of `pK_(a)` : `B lt C lt A lt D` Conjugate base is destabilized by +M of –OMe, hence least acidic
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VMC MODULES ENGLISH-JEE MAIN REVISION TEST - 4 JEE - 2020-CHEMISTRY
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