The correct option with respect to the Pauling electronegativity values of the elements is :

Options

A. `P gt S`
B. `Te gt Se`
C. `Si lt Al`
D. `Ga lt Ge`

Explanation

To solve the question regarding the correct options with respect to the Pauling electronegativity values of elements, we will analyze the trends in electronegativity across different groups of the periodic table.

### Step-by-Step Solution:

1. **Understanding Electronegativity**:
- Electronegativity is the tendency of an atom to attract shared pairs of electrons in a chemical bond. The Pauling scale is commonly used to quantify electronegativity values.

2. **Trends in Electronegativity**:
- **Down a Group**: Electronegativity decreases as you move down a group in the periodic table. This is due to the increase in atomic size, which leads to a decrease in the effective nuclear charge felt by the valence electrons.
- **Across a Period**: Electronegativity increases as you move from left to right across a period. This is because the number of protons increases, which increases the effective nuclear charge and attracts the electrons more strongly.

3. **Analyzing Specific Groups**:
- **P-Block Elements**: Let's consider the trends in the p-block elements:
- **Boron Family**: Boron (B) > Aluminum (Al) > Gallium (Ga) > Indium (In) > Thallium (Tl)
- **Carbon Family**: Carbon (C) > Silicon (Si) > Germanium (Ge) > Tin (Sn) > Lead (Pb)
- **Nitrogen Family**: Nitrogen (N) > Phosphorus (P) > Arsenic (As) > Antimony (Sb) > Bismuth (Bi)
- **Oxygen Family**: Oxygen (O) > Sulfur (S) > Selenium (Se) > Tellurium (Te) > Polonium (Po)

4. **Evaluating the Options**:
- **Option 1**: Phosphorus is more electronegative than Sulfur. **(Incorrect)** - Sulfur is more electronegative than Phosphorus.
- **Option 2**: Tellurium is more electronegative than Selenium. **(Incorrect)** - Selenium is more electronegative than Tellurium.
- **Option 3**: Aluminum is more electronegative than Silicon. **(Incorrect)** - Silicon is more electronegative than Aluminum.
- **Option 4**: Germanium is more electronegative than Gallium. **(Correct)** - Germanium is indeed more electronegative than Gallium.

5. **Conclusion**: The correct option based on the Pauling electronegativity values is **Option 4**: Germanium is more electronegative than Gallium.