Home
Class 12
CHEMISTRY
The reaction, MgO(s) + C(s) to Mg(s) +...

The reaction,
`MgO(s) + C(s) to Mg(s) + CO(g),` for which `Delta_(r)H^(@)= +491.1 " " kJ " " mol^(-1)` and `Delta_(r)S^(@)= 198.0 JK^(-1)mol^(-1)`, is not feasible at 289 K . Temperature above which reaction will be feasible is :

A

`2480.3 K `

B

`1890.0K `

C

`2380.5K`

D

`2040.5K `

Text Solution

AI Generated Solution

The correct Answer is:
To determine the temperature above which the reaction \[ \text{MgO(s) + C(s) } \rightarrow \text{ Mg(s) + CO(g)} \] is feasible, we will use the Gibbs free energy equation: \[ \Delta G^\circ = \Delta H^\circ - T \Delta S^\circ \] ### Step 1: Understand the conditions for feasibility For the reaction to be feasible, the Gibbs free energy change (\(\Delta G^\circ\)) must be less than zero: \[ \Delta G^\circ < 0 \] ### Step 2: Substitute the known values We know from the problem statement: - \(\Delta H^\circ = +491.1 \, \text{kJ/mol} = 491100 \, \text{J/mol}\) (convert kJ to J) - \(\Delta S^\circ = 198.0 \, \text{J/K·mol}\) Substituting these values into the Gibbs free energy equation gives: \[ 491100 - T \cdot 198 < 0 \] ### Step 3: Rearrange the equation Rearranging the inequality to solve for \(T\): \[ 491100 < T \cdot 198 \] \[ T > \frac{491100}{198} \] ### Step 4: Calculate the temperature Now, we perform the division: \[ T > \frac{491100}{198} \approx 2475.76 \, \text{K} \] ### Step 5: Conclusion Thus, the temperature above which the reaction will be feasible is approximately: \[ T > 2475.76 \, \text{K} \] ### Final Answer The temperature above which the reaction will be feasible is **approximately 2476 K**. ---

To determine the temperature above which the reaction \[ \text{MgO(s) + C(s) } \rightarrow \text{ Mg(s) + CO(g)} \] is feasible, we will use the Gibbs free energy equation: \[ \Delta G^\circ = \Delta H^\circ - T \Delta S^\circ ...
Promotional Banner

Topper's Solved these Questions

  • JEE MAIN REVISION TEST 5 (2020)

    VMC MODULES ENGLISH|Exercise CHEMISTRY (SECTION 2)|5 Videos
  • JEE MAIN REVISION TEST 11 (2020)

    VMC MODULES ENGLISH|Exercise CHEMISTRY (SECTION - 2)|5 Videos
  • JEE MAIN REVISION TEST 8 (2020)

    VMC MODULES ENGLISH|Exercise CHEMISTRY (SECTION 2)|5 Videos

Similar Questions

Explore conceptually related problems

Predict whether it is possible or not to reduce magnesium oxide using carbon at 298K according to the reaction. MgO(s) +C(s) rarr Mg(s) +CO(g) Delta_(r)H^(Theta) = +491.18 kJ mol^(-1) and Delta_(r)S^(Theta) = 197.67 J K^(-1) mol^(-1) If not at what temperature, the reaction becomes spontaneous.

A process has Delta H = 8 K J mol^(-1) " and " Delta S = 80JK^(-1) mol^(-1) The temperature at which the process will be in equilibrium is ____________ K.

For a reaction, P+Q rarr R+S . The value of DeltaH^(@) is -"30 kJ mol"^(-1) and DeltaS" is "-"100 J K"^(-1)"mol"^(-1) . At what temperature the reaction will be at equilibrium?

It is planned to carry out the reaction: CaCO_(3)(s) hArr CaO(s) +CO_(2)(g) at 1273K and 1 bar pressure. Delta_(r)G^(Theta) = 176 kJ mol^(-1) and Delta_(r)S^(Theta) = 157.2 kJ mol^(-1) a. Is the reaction spontaneous at this temperature and pressure ? b. Calculate the value of i. K_(p) at 1273K for the reaction ii. partial pressure of CO_(2) at equilibrium

Delta_(vap)H = 30 kJ mol^(-1) and Delta_(vap)S = 75Jmol^(-1)K^(-1) . Find the temperature of vapour, at 1 atm.

Calculate the standard free energy change for the following reaction at 27^@C . H_2(g) + I_2(g) to 2HI(g) , DeltaH^@ = + 51.9 kJ [Given : DeltaS_(H_2)^@ = 130.6 JK^(-1) mol^(-1) DeltaS_(I_2)^@ = 116.7 JK^(-1) mol^(-1) DeltaS_(HI)^@ = 206.3 JK^(-1) mol^(-1)] . Predict whether the reaction is feasible at 27°C or not.

For the reaction at 300 K A(g)hArrV(g)+S(g) Delta_(r)H^(@)=-30kJ//mol, Delta_(r)S^(@)=-0.1kJK^(-1).mol^(-1) What is the value of equilibrium constant ?

For a reversible reaction A hArr B . Find (log_(10)K)/(10) at 2727^(@) C temperature Given Delta_(r)H^(0) = - 54.07 kJ mol^(-1) Delta_(r)S^(0) = 10 JK^(-1) R = 8.314 JK^(-1) mol^(-1)

For the reaction Ag_(2)O(s)rarr 2Ag(s)+1//2O_(2)(g) the value of Delta H=30.56 KJ mol^(_1) and Delta S = 66 JK^(-1)mol^(-1) . The temperature at which the free energy change for the reaction will be zero is :-

For a hypothetical reaction A(g) + 3B(g) to 2C(g). Delta H = -100 kJ and Delta S = -200 Jk^(-1) . Then the temperature at which the reaction will be in equilibrium is