Which one of the following is likely to give a precipitate with `AgNO_(3)` solution ?

Options

A. `"CC"l_(4)`
B. `(CH_(3))_(3)"CC"l`
C. `CHCl_(3)`
D. `CH_(2)=CH-Cl`

Explanation

To determine which compound is likely to give a precipitate with AgNO₃ solution, we need to identify which compound can release Cl⁻ ions, as AgNO₃ reacts with Cl⁻ to form AgCl, a white precipitate.

### Step-by-Step Solution:

1. **Understand the Reaction**: AgNO₃ reacts with chloride ions (Cl⁻) to form a precipitate of silver chloride (AgCl). Therefore, we need to find a compound that can release Cl⁻ ions in solution.

2. **Analyze the Options**: The given options are:
- CCl₄ (Carbon Tetrachloride)
- CH₃CCl₃ (1,1,1-Trichloroethane)
- CCl₃ (Trichloromethyl)
- CHCl₃ (Chloroform)
- CH₂=CHCl (Vinyl Chloride)

3. **Evaluate Each Compound**:
- **CCl₄**: This compound is stable and does not release Cl⁻ ions.
- **CH₃CCl₃**: This compound can potentially release Cl⁻ ions, but it is a stable molecule and does not readily dissociate to form Cl⁻.
- **CCl₃**: This is a trichloromethyl group and does not release Cl⁻ ions.
- **CHCl₃**: Chloroform is stable and does not dissociate to release Cl⁻ ions.
- **CH₂=CHCl**: Vinyl chloride can undergo reactions that might lead to the release of Cl⁻ ions, especially under certain conditions.

4. **Identify the Most Likely Candidate**: Among the options, **CH₂=CHCl (Vinyl Chloride)** is the most likely to release Cl⁻ ions due to its structure and potential for reactivity.

5. **Conclusion**: Therefore, the compound that is likely to give a precipitate with AgNO₃ solution is **CH₂=CHCl (Vinyl Chloride)**.

### Final Answer:
**CH₂=CHCl (Vinyl Chloride)** is likely to give a precipitate with AgNO₃ solution.