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In the following reaction, xA rarryB ...

In the following reaction, `xA rarryB`
`log_(10)[-(d[A])/(dt)]=log_(10)[(d([B]))/(dt)]+0.3010` ‘A’ and ‘B’ respectively can be:

A

`C_(2)H_(2) and C_(6)H_(6)`

B

`2C_(2)H_(4) and C_(4)H_(8)`

C

`N_(2)O_(4) and NO_(2)`

D

n - Butane and iso - butane

Text Solution

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The correct Answer is:
To solve the problem, we start with the given equation: \[ \log_{10}\left[-\frac{d[A]}{dt}\right] = \log_{10}\left[\frac{d[B]}{dt}\right] + 0.3010 \] ### Step 1: Understand the logarithmic relationship The equation can be interpreted using properties of logarithms. The term \(0.3010\) is equivalent to \(\log_{10}(2)\), since \(10^{0.3010} \approx 2\). Therefore, we can rewrite the equation as: \[ \log_{10}\left[-\frac{d[A]}{dt}\right] = \log_{10}\left[\frac{d[B]}{dt}\right] + \log_{10}(2) \] ### Step 2: Use properties of logarithms Using the property of logarithms that states \(\log(a) + \log(b) = \log(ab)\), we can combine the right-hand side: \[ \log_{10}\left[-\frac{d[A]}{dt}\right] = \log_{10}\left[2 \cdot \frac{d[B]}{dt}\right] \] ### Step 3: Remove the logarithm By taking the antilogarithm of both sides, we can eliminate the logarithm: \[ -\frac{d[A]}{dt} = 2 \cdot \frac{d[B]}{dt} \] ### Step 4: Rearranging the equation Rearranging this equation gives us: \[ \frac{d[A]}{dt} = -2 \cdot \frac{d[B]}{dt} \] ### Step 5: Interpret the stoichiometry This relationship indicates that for every 2 moles of \(B\) produced, 1 mole of \(A\) is consumed. This suggests a stoichiometric ratio of: \[ A \rightarrow 2B \] ### Conclusion Thus, the chemical reaction can be represented as: \[ 2A \rightarrow B \] From the options given, we can conclude that the correct answer is that \(A\) and \(B\) are related by a stoichiometric coefficient of 2 for \(A\) and 1 for \(B\).

To solve the problem, we start with the given equation: \[ \log_{10}\left[-\frac{d[A]}{dt}\right] = \log_{10}\left[\frac{d[B]}{dt}\right] + 0.3010 \] ### Step 1: Understand the logarithmic relationship The equation can be interpreted using properties of logarithms. The term \(0.3010\) is equivalent to \(\log_{10}(2)\), since \(10^{0.3010} \approx 2\). Therefore, we can rewrite the equation as: ...
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