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CH(3)-CH=CH(2)overset(Cl(2)//H(2)O)to ...

`CH_(3)-CH=CH_(2)overset(Cl_(2)//H_(2)O)to`
The correct product is

A

B

`CH_(3)-underset(Cl)underset("|")"CH"-underset(Cl)underset(|)"CH"_(2)`

C

D

`H_(3)C-underset(OH)underset("| ")"CH"-underset(Cl)underset("|")"CH"_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of propene (CH₃-CH=CH₂) with chlorine (Cl₂) and water (H₂O), we will follow the steps of the reaction mechanism: ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants are propene (CH₃-CH=CH₂) and the reagents Cl₂ and H₂O. 2. **Formation of Cyclic Halonium Ion**: When Cl₂ is added to the double bond of propene, one of the chlorine atoms forms a bond with one of the carbon atoms in the double bond. This results in the formation of a cyclic halonium ion. The structure can be represented as: \[ \text{CH}_3-\text{C}^+(\text{Cl})-\text{CH}_2 \] Here, the positive charge is on the carbon that is bonded to the chlorine atom. **Hint**: Look for the formation of a cyclic structure when halogens add to alkenes. 3. **Nucleophilic Attack by Water**: Water (H₂O), which acts as a nucleophile, attacks the more substituted carbon of the cyclic halonium ion. The oxygen atom of water donates a pair of electrons to form a bond with the positively charged carbon, leading to the opening of the cyclic structure. 4. **Formation of Alcohol**: The product formed after the nucleophilic attack is a chlorohydrin. The structure can be represented as: \[ \text{CH}_3-\text{C}(\text{OH})-\text{CH}_2\text{Cl} \] Here, the OH group from water adds to the carbon that was not bonded to chlorine. 5. **Final Product**: The final product of the reaction is 2-chloropropanol (CH₃-CHOH-CH₂Cl), where the hydroxyl group (OH) and the chlorine atom (Cl) are added to adjacent carbons. ### Conclusion: The correct product formed from the reaction of propene with Cl₂ and water is 2-chloropropanol (CH₃-CHOH-CH₂Cl). ### Final Answer: The correct product is **2-chloropropanol**.

To solve the question regarding the reaction of propene (CH₃-CH=CH₂) with chlorine (Cl₂) and water (H₂O), we will follow the steps of the reaction mechanism: ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants are propene (CH₃-CH=CH₂) and the reagents Cl₂ and H₂O. 2. **Formation of Cyclic Halonium Ion**: ...
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