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The magnetic moment of two dioxygen spec...

The magnetic moment of two dioxygen species x and y are 2.83 & 1.73 BM Which of the following option is always correct about the above species.

A

Bon order of `x gt y `

B

Bond order of `y gtx `

C

x is`O_(2)` and y is `O_(2)^(-)`

D

x is`O_(2)`

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The correct Answer is:
To solve the problem regarding the magnetic moments of two dioxygen species (x and y) with values of 2.83 and 1.73 Bohr Magnetons (BM), we will follow these steps: ### Step 1: Understand the formula for magnetic moment The magnetic moment (μ) can be calculated using the formula: \[ \mu = \sqrt{n(n + 2)} \] where \( n \) is the number of unpaired electrons. ### Step 2: Calculate the number of unpaired electrons for species y (1.73 BM) Given that the magnetic moment for species y is 1.73 BM, we can set up the equation: \[ \sqrt{n(n + 2)} = 1.73 \] Squaring both sides gives: \[ n(n + 2) = (1.73)^2 \] Calculating \( (1.73)^2 \): \[ (1.73)^2 = 2.9929 \approx 3 \] So, we have: \[ n(n + 2) = 3 \] ### Step 3: Solve the quadratic equation This can be rearranged to form a quadratic equation: \[ n^2 + 2n - 3 = 0 \] Factoring the quadratic: \[ (n - 1)(n + 3) = 0 \] Thus, \( n = 1 \) (since \( n \) cannot be negative). ### Step 4: Identify species y Species y has 1 unpaired electron. The dioxygen species with 1 unpaired electron is \( O_2^- \) (superoxide ion), which has 17 electrons. ### Step 5: Calculate the number of unpaired electrons for species x (2.83 BM) Now, for species x with a magnetic moment of 2.83 BM: \[ \sqrt{n(n + 2)} = 2.83 \] Squaring both sides gives: \[ n(n + 2) = (2.83)^2 \] Calculating \( (2.83)^2 \): \[ (2.83)^2 = 8.0089 \approx 8 \] So, we have: \[ n(n + 2) = 8 \] ### Step 6: Solve the quadratic equation for species x This can be rearranged to form another quadratic equation: \[ n^2 + 2n - 8 = 0 \] Factoring the quadratic: \[ (n - 2)(n + 4) = 0 \] Thus, \( n = 2 \) (since \( n \) cannot be negative). ### Step 7: Identify species x Species x has 2 unpaired electrons. The dioxygen species with 2 unpaired electrons is \( O_2 \) (molecular oxygen), which has 16 electrons. ### Conclusion - Species x is \( O_2 \) with 2 unpaired electrons. - Species y is \( O_2^- \) with 1 unpaired electron. ### Final Answer The correct option regarding the above species is that species x is \( O_2 \) and species y is \( O_2^- \). ---

To solve the problem regarding the magnetic moments of two dioxygen species (x and y) with values of 2.83 and 1.73 Bohr Magnetons (BM), we will follow these steps: ### Step 1: Understand the formula for magnetic moment The magnetic moment (μ) can be calculated using the formula: \[ \mu = \sqrt{n(n + 2)} \] where \( n \) is the number of unpaired electrons. ...
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