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What is the final product of following r...

What is the final product of following reaction ?
Isopropyl alcohol `overset((i)SOCl_2)underset((ii)Mg//"ether")to` ?
(iii) `CH_3-CHO`
(iv) `H_3O^+`
(v) `K_2Cr_2O_7//H^+`

A

B

C

D

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The correct Answer is:
To determine the final product of the given reaction sequence starting from isopropyl alcohol, we will go through each step methodically. ### Step 1: Conversion of Isopropyl Alcohol to Isopropyl Chloride - **Reaction**: Isopropyl alcohol (CH₃CHOHCH₃) is treated with thionyl chloride (SOCl₂). - **Mechanism**: 1. The alcohol group (-OH) reacts with SOCl₂, leading to the formation of isopropyl chloride (CH₃CHClCH₃) and the by-products SO₂ and HCl. **Product after Step 1**: Isopropyl chloride (CH₃CHClCH₃) ### Step 2: Formation of Grignard Reagent - **Reaction**: Isopropyl chloride is treated with magnesium (Mg) in dry ether. - **Mechanism**: 1. The isopropyl chloride reacts with magnesium to form isopropyl magnesium chloride (CH₃C(CH₃)MgCl). **Product after Step 2**: Isopropyl magnesium chloride (CH₃C(CH₃)MgCl) ### Step 3: Reaction with Acetaldehyde - **Reaction**: The Grignard reagent (isopropyl magnesium chloride) is treated with acetaldehyde (CH₃CHO). - **Mechanism**: 1. The nucleophilic carbon of the Grignard reagent attacks the carbonyl carbon of acetaldehyde, forming a new carbon-carbon bond. 2. This results in the formation of a tertiary alcohol after hydrolysis. **Product after Step 3**: 2-Pentanol (CH₃C(CH₃)(CH₂OH)CH₃) ### Step 4: Hydrolysis - **Reaction**: The product from Step 3 undergoes hydrolysis in the presence of H₃O⁺. - **Mechanism**: 1. The Grignard reagent reacts with water, replacing the magnesium halide with a hydroxyl group (-OH). **Product after Step 4**: 2-Pentanol (CH₃C(CH₃)(OH)CH₃) ### Step 5: Oxidation - **Reaction**: 2-Pentanol is oxidized using potassium dichromate (K₂Cr₂O₇) in acidic conditions (H⁺). - **Mechanism**: 1. The secondary alcohol (2-pentanol) is oxidized to a ketone (3-pentanone). **Final Product**: 3-Pentanone (CH₃C(=O)CH₂CH₃) ### Summary of the Reaction Sequence: 1. Isopropyl alcohol (CH₃CHOHCH₃) + SOCl₂ → Isopropyl chloride (CH₃CHClCH₃) 2. Isopropyl chloride + Mg (dry ether) → Isopropyl magnesium chloride (CH₃C(CH₃)MgCl) 3. Isopropyl magnesium chloride + CH₃CHO → 2-Pentanol (CH₃C(CH₃)(OH)CH₃) 4. 2-Pentanol + H₃O⁺ → 2-Pentanol (remains the same) 5. 2-Pentanol + K₂Cr₂O₇/H⁺ → 3-Pentanone (CH₃C(=O)CH₂CH₃) ### Final Answer: The final product of the reaction sequence is **3-Pentanone (CH₃C(=O)CH₂CH₃)**. ---

To determine the final product of the given reaction sequence starting from isopropyl alcohol, we will go through each step methodically. ### Step 1: Conversion of Isopropyl Alcohol to Isopropyl Chloride - **Reaction**: Isopropyl alcohol (CH₃CHOHCH₃) is treated with thionyl chloride (SOCl₂). - **Mechanism**: 1. The alcohol group (-OH) reacts with SOCl₂, leading to the formation of isopropyl chloride (CH₃CHClCH₃) and the by-products SO₂ and HCl. **Product after Step 1**: Isopropyl chloride (CH₃CHClCH₃) ...
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VMC MODULES ENGLISH-JEE MAIN REVISION TEST - 29 (2020)-CHEMISTRY
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