Home
Class 12
CHEMISTRY
The hydrogen -like species Li^(2+) is i...

The hydrogen -like species ` Li^(2+)` is in a spherically symmetric state ` S_1` whth one radisal node . Upon absorbing light the ion undergoes transitoj ot a state ` S_2` has one radial node and its enrgy is equal to the groun sate energy of hhe hydrogen atom.
The orbital angular momentum quantum number of the state ` s_2` is :

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine the orbital angular momentum quantum number (L) of the state \( S_2 \) of the hydrogen-like ion \( Li^{2+} \) after it transitions from state \( S_1 \). ### Step-by-Step Solution: 1. **Understand the given information**: - The ion \( Li^{2+} \) is in a state \( S_1 \) with one radial node. - After absorbing light, it transitions to state \( S_2 \) which also has one radial node and its energy is equal to the ground state energy of the hydrogen atom. 2. **Use the formula for radial nodes**: - The formula for the number of radial nodes \( n - L - 1 \) is given, where \( n \) is the principal quantum number and \( L \) is the orbital angular momentum quantum number. 3. **Set up the equation for the radial node**: - Since \( S_2 \) has one radial node, we can set up the equation: \[ n - L - 1 = 1 \] - Rearranging gives: \[ n - L = 2 \quad \text{(Equation 1)} \] 4. **Determine the principal quantum number \( n \)**: - The energy of state \( S_2 \) is equal to the ground state energy of hydrogen, which is given by: \[ E = -\frac{13.6 Z^2}{n^2} \] - For hydrogen, \( Z = 1 \) and its ground state energy is \( -13.6 \) eV, so we can equate the energies for \( Li^{2+} \) (where \( Z = 3 \)): \[ -\frac{13.6 \cdot 3^2}{n^2} = -13.6 \] - Simplifying gives: \[ 9 = n^2 \implies n = 3 \] 5. **Substitute \( n \) back into Equation 1**: - Now substitute \( n = 3 \) into Equation 1: \[ 3 - L = 2 \] - Solving for \( L \): \[ L = 1 \] 6. **Identify the orbital type**: - Since \( L = 1 \), this corresponds to a \( p \) orbital. ### Conclusion: The orbital angular momentum quantum number \( L \) of the state \( S_2 \) is \( 1 \).

To solve the problem, we need to determine the orbital angular momentum quantum number (L) of the state \( S_2 \) of the hydrogen-like ion \( Li^{2+} \) after it transitions from state \( S_1 \). ### Step-by-Step Solution: 1. **Understand the given information**: - The ion \( Li^{2+} \) is in a state \( S_1 \) with one radial node. - After absorbing light, it transitions to state \( S_2 \) which also has one radial node and its energy is equal to the ground state energy of the hydrogen atom. ...
Promotional Banner

Topper's Solved these Questions

  • ATOMIC STRUCTURE

    VMC MODULES ENGLISH|Exercise JEE Main (Archive)|39 Videos
  • ATOMIC STRUCTURE

    VMC MODULES ENGLISH|Exercise JEE Advanced (Archive )|67 Videos
  • ATOMIC STRUCTURE

    VMC MODULES ENGLISH|Exercise LEVEL - 2|50 Videos
  • AMINES

    VMC MODULES ENGLISH|Exercise IN CHAPTER EXERCISE H|10 Videos
  • CHEMICAL BONDING & CHEMICAL STRUCTURE

    VMC MODULES ENGLISH|Exercise IMPECCABLE|50 Videos

Similar Questions

Explore conceptually related problems

The hydrogen -like species Li^(2+) is in a spherically symmetric state S_(1) with one node. Upon absorbing light , the ion undergoes transition to a state S_(2) . The state S_(2) has one radial node and its energy is equal is to the ground state energy of the hydrogen atom. The orbital angular momentum quantum number of the state S_(2) is

The hydrogen -like species Li^(2+) is in a spherically symmetric state S_(1) with one node. Upon absorbing light , the ion undergoes transition to a state S_(2) . The state S_(2) has one radial node and its energy is equal is to the ground state energy of the hydrogen atom. The sate S_(1) is

The hydrogen -like species Li^(2+) is in a spherically sysmmetric state S_(1) with one node ,Upon ansorbing light , the ion undergoes transition to a state S_(2) The state s_(2) has one radial node and its energy is equal is to the ground state energy of the hydrogen atom The sate S_(1) is

The hydrogen -like species Li^(2+) is in a spherically symmetric state S_(1) with one node. Upon absorbing light , the ion undergoes transition to a state S_(2) . The state S_(2) has one radial node and its energy is equal is to the ground state energy of the hydrogen atom. Energy of the state S_(1) in units of the hydrogen atom ground state energy is

The hydrogen -like species Li^(2+) is in a spherically sysmmetric state S_(1) with one node ,Upon ansorbing light , the ion undergoes transition to a state S_(2) The state s_(2) has one radial node and its energy is equal is to the ground state energy of the hydrogen atom Energy of the state S_(1) in units of the hydrogen atom ground state enegy is

A hydrogen atom in ground state absorbs 10.2eV of energy .The orbital angular momentum of the electron is increases by

What is the energy in eV requried to excite the electron from n=1 to n=2 state in hydrogen atom? (n=principal quantum number)

An orbital electron is the ground state of hydrogen has the magnetic moment mu_1 . This orbital electron is excited to 3rd excited state by some energy transfer to the hydrogen atom. The new magnetic moment fo the electron is mu_2 then

An electron in a hydrogen atom in its ground state absorbs energy equal to ionisation energy of Li^(+2) . The wavelength of the emitted electron is :-

An orbit electron in the ground state of hydrogen has an angular momentum L_(1) , and an orbital electron in the first orbit in the ground state of lithium (dounle ionised positively) has an angular momentum L_(2) . Then :

VMC MODULES ENGLISH-ATOMIC STRUCTURE-LEVEL - 2 ( Numerical value type for JEE Main )
  1. A certain day absorbs lights of lamda=400 nm and then fluorescence lig...

    Text Solution

    |

  2. How many electrons in Cu have azimuthal quantum number equal to zero?

    Text Solution

    |

  3. The hydrogen -like species Li^(2+) is in a spherically symmetric stat...

    Text Solution

    |

  4. The maximum number of electrons that can have principal quantum number...

    Text Solution

    |

  5. Maximum number of electrons in an orbital having n = 4 and l = 2 are ...

    Text Solution

    |

  6. To which quantum level does the electron jump in H atom from the lowes...

    Text Solution

    |

  7. An electron in the first excited state of H atom absorbed a photon ...

    Text Solution

    |

  8. A single electron orbits around a stationary nucleus of charge +Ze. It...

    Text Solution

    |

  9. Estimate the difference in energy between 1st and 2nd Bohr orbits for ...

    Text Solution

    |

  10. How many number of atomic orbitals associated with M-shell?

    Text Solution

    |

  11. The number of d electrons in Fe^(2+) (atomic number of Fe = 26) is eq...

    Text Solution

    |

  12. If the uncertainties in position and momentum are equal, the uncertain...

    Text Solution

    |

  13. How many atomic orbitals of the following have more than one node? 1...

    Text Solution

    |

  14. Number of waves made by a Bohr electron in one complete in its fourth ...

    Text Solution

    |

  15. The orbital angular momentum of electron in 4s orbitals is

    Text Solution

    |

  16. How many of the following atomic orbitals of H atom are degenerate? ...

    Text Solution

    |