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From the following statements concerning...

From the following statements concerning ideal gas at any given temperature T, select the correct one (s)

A

The coefficient of volume expansion at constant pressure is the same for all ideal gases

B

The average translational kinetic energy per molecule of oxygen gas is 3kT, k being Boltzmann constant

C

The mean-free path of molecules increases with increases in the pressure

D

In a gaseous mixture, the average translational kinetic energy of the molecules of each component is different

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The correct Answer is:
To solve the question regarding the statements about an ideal gas at a given temperature T, we will analyze each statement one by one. ### Step-by-Step Solution: 1. **Statement A**: "The coefficient of the volume expansion at a constant pressure is the same for all ideal gases." - **Analysis**: The coefficient of volume expansion (β) at constant pressure is defined as: \[ \beta = \frac{1}{V} \left( \frac{\partial V}{\partial T} \right)_P \] For ideal gases, this coefficient is indeed the same for all ideal gases and is given by \( \frac{R}{P} \) where R is the gas constant and P is the pressure. - **Conclusion**: This statement is **correct**. 2. **Statement B**: "The average translational kinetic energy per molecule of oxygen K gas is 3 kT." - **Analysis**: The average translational kinetic energy (E) per molecule of an ideal gas is given by: \[ E = \frac{3}{2} kT \] Therefore, the statement that it is \( 3 kT \) is incorrect. - **Conclusion**: This statement is **incorrect**. 3. **Statement C**: "The mean free path of molecules increases with increasing pressure." - **Analysis**: The mean free path (λ) is given by: \[ \lambda = \frac{kT}{\sqrt{2} \pi d^2 P} \] where d is the diameter of the gas molecules. As pressure (P) increases, the mean free path decreases because they are inversely related. - **Conclusion**: This statement is **incorrect**. 4. **Statement D**: "In a gaseous mixture, the average translational kinetic energy of the molecules of each component is different." - **Analysis**: In a gaseous mixture, all components at the same temperature have the same average translational kinetic energy given by \( \frac{3}{2} kT \). Thus, the average kinetic energy is the same for all components. - **Conclusion**: This statement is **incorrect**. ### Summary of Results: - Statement A: Correct - Statement B: Incorrect - Statement C: Incorrect - Statement D: Incorrect ### Final Answer: The correct statement concerning ideal gas at any given temperature T is **Statement A**.
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VMC MODULES ENGLISH-GASEOUS STATE & THERMODYNAMICS-JEE ADVANCED (ARCHIVE )
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