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A vessel containing one gram -mole of ox...

A vessel containing one gram -mole of oxygen is enclosed in a thermally insulated vessel. The vessel is next moved with a constant speed `v_(0)` and then suddenly stopped. The process results in a rise in the temperature of the gas by `1^(@)c`. Calculate the speed `v_(0)`.

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To solve the problem, we need to determine the speed \( v_0 \) of a vessel containing one gram-mole of oxygen that results in a temperature rise of \( 1^\circ C \) when the vessel is suddenly stopped. ### Step-by-Step Solution: 1. **Understanding the Problem**: - We have 1 gram-mole of oxygen in a thermally insulated vessel. - The vessel is moving with a constant speed \( v_0 \) and is then suddenly stopped. - This stopping leads to a temperature rise of \( 1^\circ C \). 2. **Using the First Law of Thermodynamics**: - In a thermally insulated system, the change in internal energy (\( \Delta U \)) is equal to the work done on the system. - The work done on the gas when the vessel is stopped can be equated to the change in internal energy, which is related to the temperature change. 3. **Kinetic Energy**: - The kinetic energy (KE) of the gas when moving at speed \( v_0 \) is given by: \[ KE = \frac{1}{2} mv_0^2 \] - Here, \( m \) is the mass of the gas. 4. **Change in Internal Energy**: - The change in internal energy due to the temperature change can be expressed as: \[ \Delta U = n C_v \Delta T \] - Where \( n \) is the number of moles, \( C_v \) is the specific heat at constant volume, and \( \Delta T \) is the change in temperature. 5. **Specific Heat for Oxygen**: - For one mole of oxygen, \( n = 1 \). - The specific heat at constant volume \( C_v \) for a diatomic gas like oxygen is given by: \[ C_v = \frac{R}{\gamma - 1} \] - Where \( R \) is the universal gas constant \( (R = 8.314 \, \text{J/(mol K)}) \) and \( \gamma \) (the ratio of specific heats) for oxygen is approximately \( 1.41 \). 6. **Substituting Values**: - The temperature change \( \Delta T = 1^\circ C = 1 \, \text{K} \). - Substitute \( C_v \) into the internal energy equation: \[ \Delta U = 1 \cdot \frac{R}{\gamma - 1} \cdot 1 \] - Thus, \[ \Delta U = \frac{R}{\gamma - 1} \] 7. **Equating Kinetic Energy and Change in Internal Energy**: - Set the kinetic energy equal to the change in internal energy: \[ \frac{1}{2} mv_0^2 = \frac{R}{\gamma - 1} \] 8. **Mass of Oxygen**: - The molar mass of oxygen is \( 32 \, \text{g/mol} \), which is \( 0.032 \, \text{kg} \) for calculations. 9. **Rearranging for \( v_0 \)**: - Rearranging gives: \[ v_0^2 = \frac{2R}{\gamma - 1} \cdot \frac{1}{m} \] - Therefore, \[ v_0 = \sqrt{\frac{2R}{\gamma - 1} \cdot \frac{1}{m}} \] 10. **Substituting Known Values**: - Substitute \( R = 8.314 \, \text{J/(mol K)} \), \( \gamma = 1.41 \), and \( m = 0.032 \, \text{kg} \): \[ v_0 = \sqrt{\frac{2 \cdot 8.314}{1.41 - 1} \cdot \frac{1}{0.032}} \] 11. **Calculating**: - Calculate the expression: \[ v_0 = \sqrt{\frac{16.628}{0.41} \cdot 31.25} \] \[ v_0 = \sqrt{16.628 \cdot 76.56} \approx \sqrt{1278.56} \approx 35.6 \, \text{m/s} \] ### Final Answer: The speed \( v_0 \) is approximately \( 35.6 \, \text{m/s} \).

To solve the problem, we need to determine the speed \( v_0 \) of a vessel containing one gram-mole of oxygen that results in a temperature rise of \( 1^\circ C \) when the vessel is suddenly stopped. ### Step-by-Step Solution: 1. **Understanding the Problem**: - We have 1 gram-mole of oxygen in a thermally insulated vessel. - The vessel is moving with a constant speed \( v_0 \) and is then suddenly stopped. - This stopping leads to a temperature rise of \( 1^\circ C \). ...
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