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The geometry of H2S and its dipole momen...

The geometry of `H_2S` and its dipole moment are

A

angular and non-zero

B

angular and zero

C

linear and non-zero

D

linear and zero

Text Solution

Verified by Experts

The correct Answer is:
A
`H_(2)S` has `sp^(3)` hybridized sulphur, therefore, angular in shape with non-zero dipole moment.
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The geometry of H_2 S and its dipole moment are :

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Polar covalent molecules exhibit dipole moment. Dipole moment is equal to the product of charge separation , q and the bond length d for the bond. Unit of dipole moment is debye. One debye is equal to 10^(-18) esu cm. Dipole moments is a vector quantity. It has both magnitude and direction. Hence, dipole moment of a molecule depends upon the relative orientation of the bond dipoles, but not on the polarity of bonds alone. A symmetrical structure shows zero dipole moment. Thus, dipole moment helps to predict the geometry of a molecules. Dipole moment values can be distinguish between cis- and trans- isomers, ortho, meta and pare-forms of a substance, etc. Q. Arrange the following compounds in increasing order of dipole moments, toluene (I), o-dichlorobenzene (II), m-dichlorobenzene (III) and p-dichlorobenzene (IV) :

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