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Molecular shape of XeF(2), BeF(2) and CF...

Molecular shape of `XeF_(2), BeF_(2) and CF_(2)` are :

A

the same, with 3, 0 and 0 lone pair of electrons respectively

B

the same, with 3, 1 and 0 lone pair of electrons respectively

C

different, with 0, 1 and 2 lone pair of electrons respectively

D

different, with 3, 0 and 1 lone pair of electrons respectively

Text Solution

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The correct Answer is:
To determine the molecular shapes of `XeF2`, `BeF2`, and `CF2`, we will analyze the number of valence electrons, bond pairs, and lone pairs for each molecule. Here’s a step-by-step solution: ### Step 1: Determine the Valence Electrons - **XeF2 (Xenon Difluoride)**: - Xenon (Xe) has 8 valence electrons. - Each Fluorine (F) has 7 valence electrons, and there are 2 fluorine atoms: 2 × 7 = 14. - Total valence electrons = 8 + 14 = 22. - **BeF2 (Beryllium Difluoride)**: - Beryllium (Be) has 2 valence electrons. - Each Fluorine (F) has 7 valence electrons, and there are 2 fluorine atoms: 2 × 7 = 14. - Total valence electrons = 2 + 14 = 16. - **CF2 (Carbon Difluoride)**: - Carbon (C) has 4 valence electrons. - Each Fluorine (F) has 7 valence electrons, and there are 2 fluorine atoms: 2 × 7 = 14. - Total valence electrons = 4 + 14 = 18. ### Step 2: Determine Bond Pairs and Lone Pairs - **XeF2**: - Xenon forms 2 bonds with fluorine atoms. - Total bond pairs = 2. - Total lone pairs = (Total valence electrons - Bonding electrons) / 2 = (22 - 4) / 2 = 9 lone pairs. - However, in the VSEPR theory, we consider only the lone pairs that affect the shape, which are 3 lone pairs. - **BeF2**: - Beryllium forms 2 bonds with fluorine atoms. - Total bond pairs = 2. - Total lone pairs = (Total valence electrons - Bonding electrons) / 2 = (16 - 4) / 2 = 6 lone pairs. - However, in this case, Be does not have any lone pairs that affect the shape, so it has 0 lone pairs. - **CF2**: - Carbon forms 2 bonds with fluorine atoms. - Total bond pairs = 2. - Total lone pairs = (Total valence electrons - Bonding electrons) / 2 = (18 - 4) / 2 = 7 lone pairs. - However, carbon has 1 lone pair that affects the shape. ### Step 3: Determine Molecular Shapes - **XeF2**: - With 2 bond pairs and 3 lone pairs, the shape is linear (due to the arrangement of lone pairs in the equatorial position). - **BeF2**: - With 2 bond pairs and 0 lone pairs, the shape is linear. - **CF2**: - With 2 bond pairs and 1 lone pair, the shape is bent. ### Summary of Shapes - **XeF2**: Linear - **BeF2**: Linear - **CF2**: Bent ### Final Answer - The molecular shapes of `XeF2`, `BeF2`, and `CF2` are linear, linear, and bent, respectively.

To determine the molecular shapes of `XeF2`, `BeF2`, and `CF2`, we will analyze the number of valence electrons, bond pairs, and lone pairs for each molecule. Here’s a step-by-step solution: ### Step 1: Determine the Valence Electrons - **XeF2 (Xenon Difluoride)**: - Xenon (Xe) has 8 valence electrons. - Each Fluorine (F) has 7 valence electrons, and there are 2 fluorine atoms: 2 × 7 = 14. - Total valence electrons = 8 + 14 = 22. ...
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Knowledge Check

  • Molecular shape of SF_(4), CF_(4) and XeF_(4) are

    A
    the same with 2, 0 and 1 lone pairs of electrons respectively
    B
    the same with 1, 1 and 1 lone pairs of electrons respectively
    C
    different with 0, 1 and 2 lone pairs of electrons respectively
    D
    different with 1, 0 and 2 lone pairs of electrons respectively.
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    A
    different with 1, 0 and 2 lone pairs of electrons on the central atom, respectively
    B
    different with 0, 1 and 2 lone pairs of electrons on the central atom, respectively
    C
    the same with 1, 1 and 1 lone pair of electrons on the central atom, respectively
    D
    the same with 2,0 and 1 lone pairs of electrons on the central atom, respectively.
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