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A metallic carbonyl M (CO)(x) is in gase...

A metallic carbonyl `M (CO)_(x)` is in gaseous state. The rate of diffusion of `CH_(4)` is 3.31 time faster than this gaseous carbonyl under identical conditions. If atomic mass of metal is 63.29, the closest integer value of X is___________.

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To solve the problem, we will use Graham's law of effusion, which states that the rate of diffusion of a gas is inversely proportional to the square root of its molar mass. ### Step-by-Step Solution: 1. **Understanding the Problem**: We know that the rate of diffusion of methane (CH₄) is 3.31 times faster than that of the metallic carbonyl \( M(CO)_x \). We need to find the value of \( x \) given that the atomic mass of the metal \( M \) is 63.29 g/mol. 2. **Using Graham's Law**: According to Graham's law: \[ \frac{\text{Rate of } CH_4}{\text{Rate of } M(CO)_x} = \sqrt{\frac{M_{M(CO)_x}}{M_{CH_4}}} \] Given that: \[ \frac{\text{Rate of } CH_4}{\text{Rate of } M(CO)_x} = 3.31 \] 3. **Calculating Molar Mass of CH₄**: The molar mass of methane (CH₄) is calculated as follows: - Carbon (C) = 12 g/mol - Hydrogen (H) = 1 g/mol × 4 = 4 g/mol - Total molar mass of CH₄ = 12 + 4 = 16 g/mol 4. **Calculating Molar Mass of \( M(CO)_x \)**: The molar mass of the metallic carbonyl \( M(CO)_x \) can be expressed as: \[ M_{M(CO)_x} = M + x \times M_{CO} \] where \( M_{CO} \) (molar mass of CO) = 12 (C) + 16 (O) = 28 g/mol. Therefore: \[ M_{M(CO)_x} = 63.29 + 28x \] 5. **Setting Up the Equation**: Substitute the values into Graham's law: \[ 3.31 = \sqrt{\frac{63.29 + 28x}{16}} \] 6. **Squaring Both Sides**: To eliminate the square root, square both sides: \[ (3.31)^2 = \frac{63.29 + 28x}{16} \] Calculate \( (3.31)^2 \): \[ 3.31^2 = 10.9561 \] Therefore: \[ 10.9561 = \frac{63.29 + 28x}{16} \] 7. **Multiplying Both Sides by 16**: Multiply both sides by 16 to isolate the numerator: \[ 10.9561 \times 16 = 63.29 + 28x \] Calculate: \[ 175.2976 = 63.29 + 28x \] 8. **Solving for \( x \)**: Rearranging the equation gives: \[ 28x = 175.2976 - 63.29 \] Calculate: \[ 28x = 112.0076 \] Dividing by 28: \[ x = \frac{112.0076}{28} \approx 4 \] 9. **Conclusion**: The closest integer value of \( x \) is 4. ### Final Answer: The closest integer value of \( x \) is **4**.

To solve the problem, we will use Graham's law of effusion, which states that the rate of diffusion of a gas is inversely proportional to the square root of its molar mass. ### Step-by-Step Solution: 1. **Understanding the Problem**: We know that the rate of diffusion of methane (CH₄) is 3.31 times faster than that of the metallic carbonyl \( M(CO)_x \). We need to find the value of \( x \) given that the atomic mass of the metal \( M \) is 63.29 g/mol. 2. **Using Graham's Law**: ...
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