Home
Class 12
CHEMISTRY
Ag^+ +NH3 hArr[Ag(NH3)]^+ K1=3.5x...

`Ag^+ +NH_3 hArr[Ag(NH_3)]^+ K_1=3.5xx10^-3` `[Ag(NH_3)]^+ +NH_3 hArr[Ag(NH_3)_2]^+ K_2=1.8xx10^-3`:}
then, the overall formation constant of `[Ag(NH_3)_2]^+` is :

A

`5.95 xx 10^(-6)`

B

`5.95 xx 10^(6)`

C

`5.95 xx 10^(-9)`

D

None of these

Text Solution

Verified by Experts

Add both equations `K = K_(1) xx K_(2)`
`K= 3.5 xx 10^(-3) xx 1.7 xx 10^(-3) = 5.95 xx 10^(-6)`
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL EQUILIBRIUM

    VMC MODULES ENGLISH|Exercise FUNDAMENTAL|49 Videos
  • CHEMICAL EQUILIBRIUM

    VMC MODULES ENGLISH|Exercise ENABLE|49 Videos
  • CHEMICAL EQUILIBRIUM

    VMC MODULES ENGLISH|Exercise JEE Main (Archive)|24 Videos
  • CHEMICAL BONDING-I & II

    VMC MODULES ENGLISH|Exercise JEE Advanced (Archive)|98 Videos
  • CHEMICAL KINETICS

    VMC MODULES ENGLISH|Exercise JEE Advanced (Archive)|52 Videos

Similar Questions

Explore conceptually related problems

Ag^(+) + NH_(3) ltimplies [Ag(NH_(3))]^(+), k_(1)=6.8 xx 10^(-5) [Ag(NH_(3))]^(+) + NH_(3) ltimplies [Ag(NH_(3))_(2)]^(+) , k_(2) = 1.6xx10^(-3) The formation constant of [Ag(NH_(3))_(2)]^(+) is :

The hybridisation of Ag in [Ag(NH_3)]_2^(+) complex is

Give the IUPAC names of the following compound [Ag(NH_3)_2]Cl

Give IUPAC name of the [Ag(NH_3)_2]Cl

Calculate the effective atomic number of silver in [Ag(NH_3)_2]^(+)

Overall formation constant of [Cu(NH_3)_4]^2+ ion is found to be 2.1 x 10^13 unit. Cu_(aq)^2 + 4NH_(3aq) ⇋ [Cu(NH_3)_4]_(aq)^(2+) Overall instability constant for [Cu(NH_3)_4]^(2+) ion shall be

Arrange the following solutions in decreasing order of [Ag^(o+)] ion: I. 1M [Ag(CN)_(2)]^(Theta) II. Saturated AgC1 III. 1M [Ag(NH_(3))_(2)]^(o+) in 0.1M NH_(3) IV. Saturated AgI (K_(sp) of AgC1 = 10^(-10), K_(sp) of AgI = 8.3 xx 10^(-17) K_(f) (formation constant) [Ag(CN_(2))]^(Theta) = 10^(21), K_(f) [Ag(NH_(3))_(2)]^(o+) = 10^(8)

Write the number of ions in the solution of following complexes [Ag(NH_3)_2]Cl

How much AgBr could dissolve in 1.0L of 0.4M NH_(3) ? Assume that Ag(NH_(3))_(2)^(o+) is the only complex formed. Given: the dissociation constant for Ag(NH_(3))_(2)^(o+) hArr Ag^(o+) + 2NH_(3) , K_(d) = 6.0 xx 10^(-8) and K_(sp)(AgBr) =5.0 xx 10^(-13) .

Given that at 25^@C [Ag(NH_(3))_(2)]^(+) +e^(0) to Ag_((s))+2NH_(3) E^(0)=0.02V and Ag^(+)+1e^(-) to Ag_((s))" " E^(0)=0.8V Hence the order of magnitude of equilibrium constant of the reaction [Ag(NH_(3))_(2)]^(+) Leftrightarrow Ag^(+) +2NH_(3) , will be (antilog 0.22=1.66)

VMC MODULES ENGLISH-CHEMICAL EQUILIBRIUM-JEE Advanced (Archive)
  1. N(2)O(4) is 25% dissociated at 37^(@)C and one atmosphere pressure. Ca...

    Text Solution

    |

  2. The equilibrium constant K(p) of the reaction: 2SO(2)+O(2) hArr 2SO(3)...

    Text Solution

    |

  3. For the reaction CO(g)+2H(2)(g)hArrCH(3)OH(g) Hydrogen gas is intr...

    Text Solution

    |

  4. For the reaction PCl(5)(g)hArrPCl(3)(g)+Cl(2)(g), the forward reaction...

    Text Solution

    |

  5. The rate of an exothermic reactions increases with increase in tempera...

    Text Solution

    |

  6. 0.15 mol of CO taken in a 2.5 L flask is maintained at 750 K alongwith...

    Text Solution

    |

  7. A 10-fold increase in pressure on the reaction N(2)(g)+3H(2)(g) hArr...

    Text Solution

    |

  8. For a gaseous reaction 2B rarr A, the equilibrium constant K(p) is ………...

    Text Solution

    |

  9. The degree of dissociation is 0.4 at 400 K and 1.0 atm for the gaseous...

    Text Solution

    |

  10. For the reversible reaction N(2)(g)+3H(2)(g) hArr 2NH(3)(g) at 500...

    Text Solution

    |

  11. At constant temperature , the equilibrium constant (KP) for the deco...

    Text Solution

    |

  12. Consider the following equilibrium in a closed container, N(2)O(4(g)...

    Text Solution

    |

  13. In the reaction equilibrium N(2)O(4) hArr 2NO(2)(g) When 5 mol of ...

    Text Solution

    |

  14. Ag^+ +NH3 hArr[Ag(NH3)]^+ K1=3.5xx10^-3 [Ag(NH3)]^+ +NH3 hArr[A...

    Text Solution

    |

  15. The thermal dissociation of equilibrium of CaCo(3)(s) is studied under...

    Text Solution

    |

  16. The % yield of ammonia as a function of time in the reaction N(2(g))+3...

    Text Solution

    |

  17. The gas phase reaction 2NO(2)(g) rarr N(2)O(4)(g) is an exothermic rea...

    Text Solution

    |

  18. Delta G^(@) at 500 K for substance 'S' in liquid state and gaseous st...

    Text Solution

    |

  19. At a certain temperture in a 5L vessel 2 moles of carbon monoxide and ...

    Text Solution

    |

  20. For the following reaction, equilibrium constant K(c) at 298 K is 1.6x...

    Text Solution

    |