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mu observed = Sigma mu(i)X(i) where mu...

`mu` observed `= Sigma mu_(i)X_(i)`
where `mu_(i)` is the dipole moment of the stable conformer and `X_(i)` is the mole fraction of that conformer.
(a) Write the stable conformer for `(Z--CH_(2)--CH--Z)` in Newman's projection. If `mu_(solution) = 1.0` D and mole fraction of the antiform `=0.82`, find the `mu` gauche form.
(b) Write the most stable meso conformer of `underset(CHDY)(underset(|)(CHDY))`
If (i) `Y = CH_(3)` about `C_(2)-C_(3)` rotation and (ii) `Y = OH`, about `C_(1)-C_(2)` rotation.

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It is given that for conformational isomers, the net dipole moment mu_(obs)=sum mu_(i)x_(i) Where mu_(obs) = obsereved dipole moment of the compound mu_(i) = dipole moment of the stable conformational isomers X_(1) = mole fraction of stable conformers of the compound Z-CH_(2)-CH_(2)-Z draw the Newman projection formula of all stable conformational isomers, if mu_(obs) = 1D, " and " X_(anti) = 0.82, " find " mu_(gauche) . Now draw the Newman projection formula of the most stable conformation of meso Y-CHD-CHD-Y. (a) If Y is CH_(3) ("rotation about "C_(2)-C_(3) " bond") (b) If Y is OH ("rotation about "C_(1)-C_(2) " bond")

VMC MODULES ENGLISH-INTRODUCTION TO ORGANIC CHEMISTRY -JEE ADVANCED ARCHIVE
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