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In the electrolysis of acidulated water,...

In the electrolysis of acidulated water, it is desired to obtain 1.12 cc of hydrogen per second under STP condition. The current to be passed is:

A

`1.93A`

B

`9.65`

C

`19.3A`

D

`0.965`

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The correct Answer is:
To solve the problem of determining the current required to obtain 1.12 cc of hydrogen per second during the electrolysis of acidulated water, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Reaction**: In the electrolysis of water, hydrogen gas (H₂) is produced at the cathode. The half-reaction for the production of hydrogen is: \[ 2H^+ + 2e^- \rightarrow H_2(g) \] This means that 2 moles of electrons are required to produce 1 mole of hydrogen gas. 2. **Volume of Hydrogen at STP**: At standard temperature and pressure (STP), 1 mole of any gas occupies 22,400 mL. Therefore, the volume of hydrogen produced from 1 mole of electrons can be calculated as follows: \[ \text{Volume of } H_2 = \frac{22400 \text{ mL}}{2} = 11200 \text{ mL} \] This means that 1 mole of electrons (1 Faraday) produces 11,200 mL of hydrogen. 3. **Calculate the Charge for 1.12 cc of Hydrogen**: We need to find out how much charge is required to produce 1.12 cc (or 1.12 mL) of hydrogen. We can set up a proportion: \[ \frac{11200 \text{ mL}}{96500 \text{ C}} = \frac{1.12 \text{ mL}}{Q} \] Here, \( Q \) is the charge in coulombs required to produce 1.12 mL of hydrogen. Rearranging gives: \[ Q = \frac{1.12 \text{ mL} \times 96500 \text{ C}}{11200 \text{ mL}} \] \[ Q = \frac{107072 \text{ C}}{11200} \approx 9.57 \text{ C} \] 4. **Calculate the Current**: The current (I) can be calculated using the formula: \[ Q = I \times t \] Given that the time (t) is 1 second, we can rearrange the formula to find the current: \[ I = \frac{Q}{t} = \frac{9.57 \text{ C}}{1 \text{ s}} \approx 9.57 \text{ A} \] 5. **Final Answer**: Therefore, the current required to obtain 1.12 cc of hydrogen per second is approximately **9.57 A**.

To solve the problem of determining the current required to obtain 1.12 cc of hydrogen per second during the electrolysis of acidulated water, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Reaction**: In the electrolysis of water, hydrogen gas (H₂) is produced at the cathode. The half-reaction for the production of hydrogen is: \[ 2H^+ + 2e^- \rightarrow H_2(g) ...
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