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In acidic medium is converted to Mn2+....

In acidic medium is converted to Mn2+. The quantity of electricity in faraday required to reduce `0.5` mole `MnO_(4)^(-)` to `Mn^(2+)` would be :

A

`2.5`

B

5

C

1

D

0.5

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The correct Answer is:
To solve the problem of calculating the quantity of electricity in Faraday required to reduce 0.5 moles of \( \text{MnO}_4^{-} \) to \( \text{Mn}^{2+} \) in acidic medium, we can follow these steps: ### Step 1: Determine the change in oxidation state of manganese In \( \text{MnO}_4^{-} \), the oxidation state of manganese (Mn) can be calculated as follows: - Let the oxidation state of Mn be \( x \). - The equation for the oxidation state is: \[ x + 4(-2) = -1 \] Simplifying this gives: \[ x - 8 = -1 \implies x = +7 \] - In \( \text{Mn}^{2+} \), the oxidation state of Mn is \( +2 \). ### Step 2: Calculate the change in oxidation state The change in oxidation state from \( +7 \) to \( +2 \) is: \[ \text{Change} = +7 - (+2) = +5 \] ### Step 3: Determine the number of electrons involved Since the change in oxidation state is \( +5 \) for one manganese atom, it means that each \( \text{MnO}_4^{-} \) ion requires 5 electrons to be reduced to \( \text{Mn}^{2+} \). ### Step 4: Calculate the total number of electrons for 0.5 moles of \( \text{MnO}_4^{-} \) For 0.5 moles of \( \text{MnO}_4^{-} \): \[ \text{Total electrons} = 0.5 \, \text{moles} \times 5 \, \text{electrons/mole} = 2.5 \, \text{electrons} \] ### Step 5: Convert the number of moles of electrons to Faraday 1 Faraday is defined as the charge of 1 mole of electrons, which is approximately \( 96500 \, \text{C} \). Therefore, the quantity of electricity in Faraday required to reduce 0.5 moles of \( \text{MnO}_4^{-} \) is: \[ \text{Quantity of electricity} = 2.5 \, \text{Faraday} \] ### Final Answer The quantity of electricity in Faraday required to reduce 0.5 moles of \( \text{MnO}_4^{-} \) to \( \text{Mn}^{2+} \) is **2.5 Faraday**. ---

To solve the problem of calculating the quantity of electricity in Faraday required to reduce 0.5 moles of \( \text{MnO}_4^{-} \) to \( \text{Mn}^{2+} \) in acidic medium, we can follow these steps: ### Step 1: Determine the change in oxidation state of manganese In \( \text{MnO}_4^{-} \), the oxidation state of manganese (Mn) can be calculated as follows: - Let the oxidation state of Mn be \( x \). - The equation for the oxidation state is: \[ x + 4(-2) = -1 ...
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