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The standard emf of a galvanic cell inv...

The standard emf of a galvanic cell involving 2 motes of electrons in its redox reaction is 0.59 V the equilibriun constant for the redox reaction of the cell is

A

`10^(20)`

B

`10^(5)`

C

10

D

`10^(10)`

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The correct Answer is:
To solve the problem of finding the equilibrium constant (K_eq) for a redox reaction in a galvanic cell with a standard EMF (E°) of 0.59 V and involving 2 moles of electrons, we can use the Nernst equation in its equilibrium form. ### Step-by-Step Solution: 1. **Understand the relationship between E° and K_eq**: The relationship between the standard EMF of the cell (E°) and the equilibrium constant (K_eq) is given by the equation: \[ E° = \frac{0.0591}{n} \log K_{eq} \] where: - E° is the standard EMF of the cell, - n is the number of moles of electrons transferred in the redox reaction, - K_eq is the equilibrium constant. 2. **Substitute the known values**: From the problem, we know: - E° = 0.59 V - n = 2 moles of electrons Plugging these values into the equation gives: \[ 0.59 = \frac{0.0591}{2} \log K_{eq} \] 3. **Rearrange the equation to solve for log K_eq**: Multiply both sides of the equation by 2: \[ 2 \times 0.59 = 0.0591 \log K_{eq} \] \[ 1.18 = 0.0591 \log K_{eq} \] 4. **Divide both sides by 0.0591**: \[ \log K_{eq} = \frac{1.18}{0.0591} \] Calculate the right side: \[ \log K_{eq} \approx 19.97 \] 5. **Convert log K_eq to K_eq**: To find K_eq, we take the antilog (base 10) of both sides: \[ K_{eq} = 10^{19.97} \] 6. **Approximate K_eq**: Since \(10^{19.97} \approx 10^{20}\), we conclude: \[ K_{eq} \approx 10^{20} \] ### Final Answer: The equilibrium constant (K_eq) for the redox reaction of the cell is approximately \(10^{20}\). ---

To solve the problem of finding the equilibrium constant (K_eq) for a redox reaction in a galvanic cell with a standard EMF (E°) of 0.59 V and involving 2 moles of electrons, we can use the Nernst equation in its equilibrium form. ### Step-by-Step Solution: 1. **Understand the relationship between E° and K_eq**: The relationship between the standard EMF of the cell (E°) and the equilibrium constant (K_eq) is given by the equation: \[ E° = \frac{0.0591}{n} \log K_{eq} ...
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