For the electrochemical cell, (M|M^(o+))...

For the electrochemical cell, `(M|M^(o+))||(X^(c-)|X),E^(c-)._((M^(o+)|M))=0.44V` and `E^(c-)._((X|X^(c-)))=0.334V`

`M+Xrightarrow M^(+) + X^` is spontaneous reaction

`M^(+)+ X^(-)rightarrow M+ X` is a spontaneous reaction

`E_(cell)= 0.77V`

Text Solution

Verified by Experts

That reaction is sponteneous where cathode is of higher reduction portential.
For `M^(+)+X^(-) to M+X,E_(cell)^(@)=0.44-0.33=0.11 V` is possitive ,hence reaction is sponteneous.

Topper's Solved these Questions

ELECTROCHEMISTRY
VMC MODULES ENGLISH|Exercise FUNDAMENTAL|50 Videos
ELECTROCHEMISTRY
VMC MODULES ENGLISH|Exercise ENABLE|50 Videos
ELECTROCHEMISTRY
VMC MODULES ENGLISH|Exercise JEE Main (Archive)|57 Videos
CLASSIFICATION OF ELEMENTS AND PERIODICITY IN PROPERTIES
VMC MODULES ENGLISH|Exercise JEE ADVANCE (ARCHIVE)|30 Videos
ENVIRONMENTAL CHEMISTRY
VMC MODULES ENGLISH|Exercise JEE Main (Archive)|39 Videos

Similar Questions

Explore conceptually related problems

For the electrochemical cell, (M|M^(o+))||(X^(c-)|X) , E^(c-)._((M^(o+)|M))=0.44V , and E^(c-)._((X|X^(c-))=-0.33V . From this data, one can conclude that

For the electrochemical cell, (M)|M^(+))||(X^(-)|X) . E^(@)(M^(+)//M)=0.44V and E^(@)(X//X^(-))=0.33V . From this data one can deduce that

For the electrochemicl cell, M|M^(+)||X^(-)|X E_((M^(+)//M))^(@) = 0.44 V and E_((X//X^(-)))^(@) = 0.33 V From this data one can deduce that :

A volataic cell consists of an electode of solide silver immerse in a 0.10M AgNO_(3) solution and an electrode of unknown metal 'X' immersed in a 0.10M solution X(NO_(3))_(2) . A porous barrier separates the two half of the cell. Also given : E^(c-)._((Ag^(o+)|Ag))=0.80V and E^(c-)._(cell)=1.05V at 25^(@)C X(s)|X^(2+)(1.0M)||Ag^(o+)(0.1M)|Ag(s) If Ag^(o+)|Ag half cell in the above voltaic cell is replaced by Zn^(2+)|Zn half cell (E^(c-)._(Zn^(2+)|Zn)=-0.76V)

E^(c-)._(red) of different half cell are given as : E^(c-)._(Cu^(2+)|Cu)=0.34V,E^(c-)._(Zn^(2+)|Zn)=-0.76V . E^(c-)._(Ag^(o+)|Ag)=0.80 V, E^(c-)._(Mg^(2+)|Mg)=-2.37V. In which cell DeltaG^(c-) is most negative ?

At 25^(@)C temperature the cell potential of a given electrochemical cell is 1.92 V Mg(s)|Mg^(2+)(Aq)x M||Fe^(2+)(aq)0.01 M |Fe(s) Given E_(Mg//mg^(2+))(Aq)=2.37 v E_(Fe//Fe^(2+))^(@)(Aq)=0.45 V Find the value of x

For the cell : Zn (s) |Zn^(2+)(a M)||Ag^(o+)(bM)|Ag(s) . a. Write Nernst equation to show how E_(cell) vary with concentration of Zn^(2+) and Ag^(o+) ions. Given E^(c-)._((Zn^(2+)|Zn))=0.76V,E^(-)._((Ag^(o+)|Ag))=0.80V. b. Find E_(cell) for [Zn^(2+)]=0.01M and [Ag^(c-)]=0.02M . c. For what values of Q will the cell EMF be i. 0.0V" "ii. 0.97 V

If excess of Zn is added to 1.0M solution of CuSO_(4) , find the concentration of Cu^(2+) ions at equilibrium. Given :E^(c-)._((Zn^(2+)|Zn))=-0.76V E^(c-)._(cell)=(E^(c-)._((Cu^(2+)|Cu))=0.34V

In the following electrochemical cell : Zn|Zn^(2+)||H^(o+)|(H_(2))Pt E_(cell)=E^(c-)._(cell). This will be when 1) [Zn^(2+)]=[H^(o+)]=1M and p_(H_(2))1 atm 2) [Zn^(2+)]=0.01 M,[H^(o+)]=0.1M, and p_(H_(2))=1atm 3) [Zn^(2+)]=1m,[H^(o+)]=0.1M, and p_(H_(2))=0.01atm 4) [Zn^(2+)]=[H^(o+)]=0.1M and p_(H_(2))=0.1 atm

Two electrochemical cells are assembled in which the following reactions occur : V^(2)=VO^(2+)+2H^(o+)rarr 2V^(3+)+H_(2)O V^(3+)+Ag^(o+)+H_(2)O rarr VO^(2+)+2H^(o+)+Ag(s) Calculate E^(c-) for half reaction V^(3+)+e^(-)rarr V^(2+) Given : E^(c-)._((Ag^(o+)|Ag))=0.799 E^(c-)=E^(c-)._(V^(4+)|V^(3+))-E^(c-)._(V^(3+)|V^(2+))=0.616V E^(c-)=E^(c-)._(Ag^(o+)|Ag)-E^(c-)._(V^(4+)|V_(3+))=0.439V

VMC MODULES ENGLISH-ELECTROCHEMISTRY-JEE Advanced (Archive)

A cell, Ag|Ag^(o+)||Cu^(2+)|Cu , initially contains 1 M Ag^(o+) and 1M...
Text Solution
|
Copper sulphate solution (250 ML) was electrolyzed using a platinum an...
Text Solution
|
For the electrochemical cell, (M|M^(o+))||(X^(c-)|X),E^(c-).((M^(o+)|M...
Text Solution
|
The following electrochemical cell has been set up Pt(1)|Fe^(3+)|Fe^...
Text Solution
|
A standard solution of KNO(3) is used to make salt bridge, because
Text Solution
|
The correct order of equivalent conductance at infinite dilution of ...
Text Solution
|
Standard electrode potential data are useful for understanding the sui...
Text Solution
|
The standart potential of the following cell is 0.23 at 15^(@)C and 0....
Text Solution
|
(a) Will pH value of water be same at temperature 25^(@)C and 4^(@)C? ...
Text Solution
|
In the electrolytic cell, flow of electrons is from
Text Solution
|
Find the equilibrium constant for the reaction Cu^(2+)+ 1n^(2+) Cu^(...
Text Solution
|
Zn|Zn^(2+)(a=0.1M)||Fe^(2+)(a=0.01M)Fe. The EMF of the above cell i...
Text Solution
|
The half cell reactions for rusting of iron are : 2H^(+) + 2e^(-) + ...
Text Solution
|
Calculate DeltaG(r)^(@) of the following reaction Ag^(+)(aq)+cI^(-)(...
Text Solution
|
2Ag^(+) + C(6)H(12) O(6) + H(2)O rightarrow 2Ag(s) + C6H(12)O(7) + 2H^...
Text Solution
|
When ammonia is added to the solution, pH is raised to 11. Which half-...
Text Solution
|
Ammonia is always added in this reaction. Which of the following must ...
Text Solution
|
We have taken a saturated solution of AgBr, whose K(sp) is 12xx10^(-14...
Text Solution
|
Among the following, identify the correct statements.
Text Solution
|
Redox reactions play a pivotal role in chemistry and biology. The valu...
Text Solution
|