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Solubility of iodine in CS2 is due to :...

Solubility of iodine in `CS_2` is due to :

A

Van der Waal's forces

B

Ionic bond formation

C

Covalent bond attraction

D

Coordinate bond interaction

Text Solution

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The correct Answer is:
To determine the solubility of iodine (I2) in carbon disulfide (CS2), we need to analyze the nature of both substances and the type of interactions that can occur between them. ### Step-by-Step Solution: 1. **Identify the Nature of Iodine (I2)**: - Iodine (I2) is a diatomic molecule consisting of two iodine atoms. - Since both atoms have the same electronegativity, the bond between them is non-polar. - Therefore, I2 is a non-polar molecule. 2. **Identify the Nature of Carbon Disulfide (CS2)**: - CS2 has a linear structure with carbon (C) bonded to two sulfur (S) atoms. - The C-S bonds have a slight electronegativity difference, but because the molecule is symmetrical, the dipoles cancel each other out. - Thus, CS2 is also a non-polar molecule. 3. **Determine the Type of Interaction**: - Since both I2 and CS2 are non-polar molecules, the primary type of interaction between them will be Van der Waals forces (also known as London dispersion forces). - These forces arise due to temporary dipoles that occur when the electron distribution around non-polar molecules becomes uneven. 4. **Eliminate Other Options**: - **Ionic Bond Formation**: This cannot occur as there are no metals involved and both molecules are non-polar. - **Covalent Bond Attraction**: There is no formation of covalent bonds between I2 and CS2 as they do not share electrons in a bond. - **Coordinate Bond Interaction**: This also does not apply since there is no donor-acceptor pair interaction between the two non-polar molecules. 5. **Conclusion**: - The solubility of iodine in CS2 is primarily due to Van der Waals forces, which facilitate the interaction between the two non-polar molecules. ### Final Answer: The solubility of iodine in CS2 is due to Van der Waals forces.
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