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In OF2, the number of bond pairs and lon...

In `OF_2`, the number of bond pairs and lone pairs of electrons are respectively,

A

2,6

B

2,8

C

2,10

D

2,9

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The correct Answer is:
To determine the number of bond pairs and lone pairs of electrons in the molecule OF₂ (oxygen difluoride), we will follow these steps: ### Step 1: Determine the Valence Electrons - Oxygen (O) has 6 valence electrons. - Each fluorine (F) atom has 7 valence electrons, and there are 2 fluorine atoms. **Calculation:** - Total valence electrons = Valence electrons of O + Valence electrons of 2 F - Total valence electrons = 6 + (2 × 7) = 6 + 14 = 20 valence electrons. ### Step 2: Identify the Central Atom - In OF₂, oxygen is the central atom because it is less electronegative than fluorine. ### Step 3: Determine the Hybridization - To find the hybridization or steric number, we can use the formula: \[ \text{Steric Number} = \frac{1}{2} \left( \text{V} + \text{M} + \text{C} - \text{A} \right) \] Where: - V = number of valence electrons of the central atom (O = 6) - M = number of monovalent atoms attached (2 F atoms = 2) - C = positive charge (0 for neutral species) - A = negative charge (0 for neutral species) **Calculation:** - Steric Number = \( \frac{1}{2} (6 + 2 + 0 - 0) = \frac{1}{2} (8) = 4 \) ### Step 4: Determine Bond Pairs and Lone Pairs - The steric number of 4 indicates that there are 4 regions of electron density around the oxygen atom. - In OF₂, oxygen forms 2 bonds with the 2 fluorine atoms, which accounts for 2 bond pairs. **Calculation of Lone Pairs:** - Total regions of electron density (4) = Bond pairs (2) + Lone pairs (X) - Therefore, \( 4 = 2 + X \) - Solving for X gives us \( X = 2 \) lone pairs. ### Step 5: Count the Total Lone Pairs - Each fluorine atom has 6 remaining valence electrons (since they each use 1 for bonding with oxygen). - Thus, each fluorine has 3 lone pairs. - Total lone pairs from fluorine = \( 2 \times 3 = 6 \) lone pairs. ### Step 6: Total Lone Pairs in the Molecule - Total lone pairs in OF₂ = Lone pairs on O + Lone pairs on F - Total lone pairs = 2 (on O) + 6 (on 2 F) = 8 lone pairs. ### Final Answer - The number of bond pairs in OF₂ is 2, and the number of lone pairs is 8. Thus, the answer is **2 bond pairs and 8 lone pairs**. ---
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