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A gas diffuses at a rate which is twice ...

A gas diffuses at a rate which is twice that of another gas B. The ratio of molecular weights of A to B is

A

1

B

0.75

C

0.5

D

0.25

Text Solution

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The correct Answer is:
To solve the problem, we will use Graham's law of diffusion, which states that the rate of diffusion of a gas is inversely proportional to the square root of its molar mass. ### Step-by-Step Solution: 1. **Understanding the Given Information**: - Let the rate of diffusion of gas A be \( R_A \) and that of gas B be \( R_B \). - According to the problem, \( R_A = 2R_B \). 2. **Applying Graham's Law of Diffusion**: - Graham's law states: \[ \frac{R_A}{R_B} = \sqrt{\frac{M_B}{M_A}} \] - Here, \( M_A \) is the molar mass of gas A and \( M_B \) is the molar mass of gas B. 3. **Substituting the Known Rate**: - Substitute \( R_A = 2R_B \) into the equation: \[ \frac{2R_B}{R_B} = \sqrt{\frac{M_B}{M_A}} \] - This simplifies to: \[ 2 = \sqrt{\frac{M_B}{M_A}} \] 4. **Squaring Both Sides**: - To eliminate the square root, square both sides of the equation: \[ 2^2 = \frac{M_B}{M_A} \] - This gives: \[ 4 = \frac{M_B}{M_A} \] 5. **Finding the Ratio of Molecular Weights**: - Rearranging the equation gives: \[ \frac{M_A}{M_B} = \frac{1}{4} \] - Therefore, the ratio of the molecular weights of A to B is: \[ M_A : M_B = 1 : 4 \] ### Final Answer: The ratio of the molecular weights of gas A to gas B is \( 1 : 4 \).
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