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For two gases, A and B with molecular we...

For two gases, A and B with molecular weights `M_(A)` and `M_(B)`. It is observed that at a certain temperature. T, the mean velocity of A is equal to the root mean square velocity of B. thus the mean velocity of A can be made equal to the mean velocity of B, if:

A

A is at temperature `T_1` and B at `T_2` and `T_1 gt T_2`

B

A is lowered to a temperature `T_1` and `T_1 lt T_2`

C

Both A & B are raised to a higher temperature

D

Both A & B are placed at a lower temperature

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The correct Answer is:
To solve the problem, we need to analyze the relationship between the mean velocity of gas A and the root mean square velocity of gas B, as well as the conditions under which their mean velocities can be made equal. ### Step-by-Step Solution: 1. **Understand the Definitions**: - The mean velocity (v̄) of a gas is given by the formula: \[ v̄ = \sqrt{\frac{8RT}{\pi M}} \] - The root mean square velocity (v_rms) of a gas is given by the formula: \[ v_{rms} = \sqrt{\frac{3RT}{M}} \] 2. **Set Up the Given Condition**: - According to the problem, the mean velocity of gas A is equal to the root mean square velocity of gas B: \[ v̄_A = v_{rms_B} \] - Substituting the formulas: \[ \sqrt{\frac{8RT}{\pi M_A}} = \sqrt{\frac{3RT}{M_B}} \] 3. **Square Both Sides**: - Squaring both sides to eliminate the square roots: \[ \frac{8RT}{\pi M_A} = \frac{3RT}{M_B} \] 4. **Cancel Common Terms**: - Since \(RT\) is common on both sides, we can cancel it out (assuming \(T\) is constant and non-zero): \[ \frac{8}{\pi M_A} = \frac{3}{M_B} \] 5. **Rearranging the Equation**: - Cross-multiplying gives: \[ 8M_B = 3\pi M_A \] - From this, we can deduce: \[ M_B = \frac{3\pi}{8} M_A \] 6. **Analyzing Molar Masses**: - Since \(3\pi \approx 9.42\), it follows that: \[ M_B > M_A \] - This means gas B has a greater molar mass than gas A. 7. **Condition for Equal Mean Velocities**: - To make the mean velocity of gas A equal to that of gas B, we need to consider the relationship of mean velocity with temperature. The mean velocity is inversely related to the square root of molar mass. - Since gas A has a lower molar mass, it will have a higher mean velocity. To make the mean velocities equal, we can lower the temperature of gas A. 8. **Conclusion**: - Therefore, the mean velocity of gas A can be made equal to the mean velocity of gas B if the temperature of gas A is reduced to a value \(T_1\) such that \(T_1 < T_2\) (where \(T_2\) is the original temperature). ### Final Answer: The mean velocity of gas A can be made equal to the mean velocity of gas B if the temperature of gas A is lowered (option 2).
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