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Heat of neutralization of strong acid ag...

Heat of neutralization of strong acid against strong base is constant and is equal to

A

13.7 kcal

B

57 kJ

C

`5.7 xx 10^(4) J`

D

All of the above

Text Solution

AI Generated Solution

The correct Answer is:
### Step-by-Step Solution: 1. **Understanding Neutralization**: - Neutralization is a chemical reaction between an acid and a base that produces a salt and water. In this case, we are considering a strong acid (HCl) and a strong base (NaOH). 2. **Identifying the Reaction**: - The reaction can be written as: \[ \text{HCl} + \text{NaOH} \rightarrow \text{NaCl} + \text{H}_2\text{O} \] - When HCl dissociates, it produces H⁺ and Cl⁻ ions, and when NaOH dissociates, it produces Na⁺ and OH⁻ ions. 3. **Net Ionic Equation**: - The net ionic equation for the neutralization reaction is: \[ \text{H}^+ + \text{OH}^- \rightarrow \text{H}_2\text{O} \] - This shows that the heat of neutralization is essentially the heat released when H⁺ ions react with OH⁻ ions to form water. 4. **Heat of Neutralization**: - The heat of neutralization for strong acids and strong bases is constant and is equal to the heat of formation of water from its ions. 5. **Value of Heat of Neutralization**: - The value of the heat of neutralization is approximately: \[ 57 \text{ kJ/mol} \] - This can also be expressed as: \[ 5.7 \times 10^4 \text{ J/mol} \] - Additionally, converting this value to kilocalories gives: \[ 57 \text{ kJ} \approx 13.7 \text{ kcal} \] 6. **Conclusion**: - Therefore, the heat of neutralization of a strong acid against a strong base is constant and equal to 57 kJ, which can also be expressed in other units as mentioned above. ### Final Answer: The heat of neutralization of a strong acid against a strong base is constant and is equal to **57 kJ** (or **5.7 x 10^4 J** or **13.7 kcal**). ---
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