Home
Class 12
CHEMISTRY
The correct thermodynamic conditions for...

The correct thermodynamic conditions for the spontaneous reaction at all temperature is

A

`triangleH lt 0 and triangleS lt 0`

B

`triangleH lt and triangleS=0`

C

`triangleH gt 0 and triangleS lt 0`

D

`triangleH lt 0 and triangleS gt 0`

Text Solution

Verified by Experts

The correct Answer is:
D
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS & THERMOCHEMISTRY

    VMC MODULES ENGLISH|Exercise Efficient|48 Videos
  • THERMODYNAMICS

    VMC MODULES ENGLISH|Exercise JEE ADVANCED (ARCHIVE)|44 Videos

Similar Questions

Explore conceptually related problems

The correct thermodnamic conditions for the spontaneous reaction at all temperature is:

State the thermodynamic conditions for spontaneous occurrence of a process.

Necessary conditions for spontanity of a reaction ________

In isolated system, find the condition for spontaneous reaction:

The signs of DeltaH,DeltaS and DeltaG for a non-spontaneous reaction at all temperature would e

Free enegry , G = H - TS , is state function that indicates whther a reaction is spontaneous or non-spontaneous. If you think of TS as the part of the system's enegry that is disordered already, then (H -TS) is the part of the system's energy that is still ordered and therefore free to cause spontaneous change by becoming disordered. Also, DeltaG = DeltaH - T DeltaS From the second law of thermodynamics, a reaction is spontaneous if Delta_("total")S is positive, non-spontaneous if Delta_("total")S is negative, and at equilibrium if Delta_('total")S is zero. Since, -T DeltaS = DeltaG and since DeltaG and DeltaS have opposite sings, we can restate the thermodynamic criterion for the spontaneity of a reaction carried out a constant temperature and pressure. IF DeltaG lt 0 , the reaction is spontaneous. If DeltaG gt 0 , the reaction is non-spontaneous. If DeltaG = 0 , the reaction is at equilibrium. Read the above paragraph carefully and answer the following questions based on the above comprehension. For the spontaneity of a reaction, which statement is true?

Free enegry , G = H - TS , is state function that indicates whther a reaction is spontaneous or non-spontaneous. If you think of TS as the part of the system's enegry that is disordered already, then (H -TS) is the part of the system's energy that is still ordered and therefore free to cause spontaneous change by becoming disordered. Also, DeltaG = DeltaH - T DeltaS From the second law of thermodynamics, a reaction is spontaneous if Delta_("total")S is positive, non-spontaneous if Delta_("total")S is negative, and at equilibrium if Delta_('total")S is zero. Since, -T DeltaS = DeltaG and since DeltaG and DeltaS have opposite sings, we can restate the thermodynamic criterion for the spontaneity of a reaction carried out a constant temperature and pressure. IF DeltaG lt 0 , the reaction is spontaneous. If DeltaG gt 0 , the reaction is non-spontaneous. If DeltaG = 0 , the reaction is at equilibrium. Read the above paragraph carefully and answer the following questions based on the above comprehension. A particular reaction has a negative value for the free energy change. Then at ordinary temperature

For an endothermic reaction to be spontaneous

Free enegry , G = H - TS , is state function that indicates whther a reaction is spontaneous or non-spontaneous. If you think of TS as the part of the system's enegry that is disordered already, then (H -TS) is the part of the system's energy that is still ordered and therefore free to cause spontaneous change by becoming disordered. Also, DeltaG = DeltaH - T DeltaS From the second law of thermodynamics, a reaction is spontaneous if Delta_("total")S is positive, non-spontaneous if Delta_("total")S is negative, and at equilibrium if Delta_('total")S is zero. Since, -T DeltaS = DeltaG and since DeltaG and DeltaS have opposite sings, we can restate the thermodynamic criterion for the spontaneity of a reaction carried out a constant temperature and pressure. IF DeltaG lt 0 , the reaction is spontaneous. If DeltaG gt 0 , the reaction is non-spontaneous. If DeltaG = 0 , the reaction is at equilibrium. Read the above paragraph carefully and answer the following questions based on the above comprehension. If an endothermic reaction is non-spontaneous at freezing point of water and becomes feasible at its boiling point, then

Free enegry , G = H - TS , is state function that indicates whther a reaction is spontaneous or non-spontaneous. If you think of TS as the part of the system's enegry that is disordered already, then (H -TS) is the part of the system's energy that is still ordered and therefore free to cause spontaneous change by becoming disordered. Also, DeltaG = DeltaH - T DeltaS From the second law of thermodynamics, a reaction is spontaneous if Delta_("total")S is positive, non-spontaneous if Delta_("total")S is negative, and at equilibrium if Delta_('total")S is zero. Since, -T DeltaS = DeltaG and since DeltaG and DeltaS have opposite sings, we can restate the thermodynamic criterion for the spontaneity of a reaction carried out a constant temperature and pressure. IF DeltaG lt 0 , the reaction is spontaneous. If DeltaG gt 0 , the reaction is non-spontaneous. If DeltaG = 0 , the reaction is at equilibrium. Read the above paragraph carefully and answer the following questions based on the above comprehension. Which of the following is true for the reaction? H_(2)O(l) hArr H_(2)O(g) at 100^(@)C and 1 atmosphere

VMC MODULES ENGLISH-THERMODYNAMICS & THERMOCHEMISTRY-Impeccable
  1. Enthalpy change for the reaction, 4H(g) to 2H2(g) is -869.6 kJ Th...

    Text Solution

    |

  2. If the enthalpy change for the transition of liquid water to steam is ...

    Text Solution

    |

  3. Based on the first law of thermodynamics, which one of the following i...

    Text Solution

    |

  4. The enthalpy of solution of sodium chloride is 4 kJ mol^(-1) and its e...

    Text Solution

    |

  5. Which reaction, with the following values of Delta H, Delta S, at 400 ...

    Text Solution

    |

  6. Enthalpy of vapourization of benzene is +35.3 kJ mol^(-1) at its boili...

    Text Solution

    |

  7. For the reversible reaction. A(s)+B(g) Leftrightarrow C(g)+D(g), tri...

    Text Solution

    |

  8. A reaction is spontaneous at low temperature but non- spontaneous at h...

    Text Solution

    |

  9. A reaction having equal energies of activation for forward and reverse...

    Text Solution

    |

  10. Which of the following statements is correct for the spontaneous adsor...

    Text Solution

    |

  11. For the reaction: X(2)O(4)(l)rarr2XO(2)(g) DeltaU=2.1kcal , DeltaS...

    Text Solution

    |

  12. Which of the following statements is correct for a reversible process ...

    Text Solution

    |

  13. The heat of combustion of carbon to CO(2)is-395.5kJ//mol.The heat rele...

    Text Solution

    |

  14. The correct thermodynamic conditions for the spontaneous reaction at a...

    Text Solution

    |

  15. Consider the following liquid-vapour equilibrium Liquid hArr Vapour...

    Text Solution

    |

  16. What is the amount of work done when 0.5 mole of methane, CH(4)(g) is ...

    Text Solution

    |

  17. Which one of the following is incorrect for ideal solution ?

    Text Solution

    |

  18. For a sample of perfect gas when its pressure is changed isothermally ...

    Text Solution

    |

  19. If the E("cell")^(@) for a given reaction has a negative value, which ...

    Text Solution

    |

  20. A gas is allowed to expand in a well insulated container against a co...

    Text Solution

    |