Home
Class 12
CHEMISTRY
In a flask colourless N2O4 is in equilib...

In a flask colourless `N_2O_4` is in equilibrium with brown coloured `NO_2`. At equilibrium, when the flask is heated at `100^@C` the brown colour deepens and on cooling it becomes less coloured. The change in enthalpy, `DeltaH` for this system is

A

negative

B

positive

C

zero

D

undefined

Text Solution

Verified by Experts

The correct Answer is:
B
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL EQUILIBRIUM

    VMC MODULES ENGLISH|Exercise IMPECCABLE|50 Videos
  • CHEMICAL EQUILIBRIUM

    VMC MODULES ENGLISH|Exercise Illustration|24 Videos
  • CHEMICAL EQUILIBRIUM

    VMC MODULES ENGLISH|Exercise ENABLE|49 Videos
  • CHEMICAL BONDING-I & II

    VMC MODULES ENGLISH|Exercise JEE Advanced (Archive)|98 Videos
  • CHEMICAL KINETICS

    VMC MODULES ENGLISH|Exercise JEE Advanced (Archive)|52 Videos

Similar Questions

Explore conceptually related problems

When a sample of NO_(2) is placed in a container, this equilibrium is rapidly estabilished. 2NO_(2)(g) hArr N_(2)O_(4)(g) Iff this equilibrium mixture is a darker colour at high temperatures annd at low pressure, which of these statements about the reaction is true?

Give the electronic configuration of the How does the colour change on heating [Ti(H_2O)_6]^(3+) ion?

Borax Bead Test is carried out when the original mixture is coloured. It is done with the help of a cleam platinum wire on which a small loop is made at the end. When borax is heated on platinum wire loop transparent glass like bead is obtained. The hot bead is brought in contact with salt till it reacts with fused borax and colour is imparted to the bead. bead colour is noted. {:("Colour of the bead","Ion"),(1." Blue green",Cu^(2+)),(2." Yellow ",Fe^(3+)),(3." Green",Cr^(3+)),(4." Violet",Mn^(2+)),(5." Dark blue",Co^(2+)),(6." Brown",Ni^(2+)):} Q. Glassy bead of :

Borax Bead Test is carried out when the original mixture is coloured. It is done with the help of a cleam platinum wire on which a small loop is made at the end. When borax is heated on platinum wire loop transparent glass like bead is obtained. The hot bead is brought in contact with salt till it reacts with fused borax and colour is imparted to the bead. bead colour is noted. {:("Colour of the bead","Ion"),(1." Blue green",Cu^(2+)),(2." Yellow ",Fe^(3+)),(3." Green",Cr^(3+)),(4." Violet",Mn^(2+)),(5." Dark blue",Co^(2+)),(6." Brown",Ni^(2+)):} Q. The flame used in Borax Bead Test is:

Borax Bead Test is carried out when the original mixture is coloured. It is done with the help of a cleam platinum wire on which a small loop is made at the end. When borax is heated on platinum wire loop transparent glass like bead is obtained. The hot bead is brought in contact with salt till it reacts with fused borax and colour is imparted to the bead. bead colour is noted. {:("Colour of the bead","Ion"),(1." Blue green",Cu^(2+)),(2." Yellow ",Fe^(3+)),(3." Green",Cr^(3+)),(4." Violet",Mn^(2+)),(5." Dark blue",Co^(2+)),(6." Brown",Ni^(2+)):} Q. Glassy bead of :

Borax Bead Test is carried out when the original mixture is coloured. It is done with the help of a cleam platinum wire on which a small loop is made at the end. When borax is heated on platinum wire loop transparent glass like bead is obtained. The hot bead is brought in contact with salt till it reacts with fused borax and colour is imparted to the bead. bead colour is noted. {:("Colour of the bead","Ion"),(1." Blue green",Cu^(2+)),(2." Yellow ",Fe^(3+)),(3." Green",Cr^(3+)),(4." Violet",Mn^(2+)),(5." Dark blue",Co^(2+)),(6." Brown",Ni^(2+)):} Q. Blue bead can be of:

When a salt is heated with dil H_(2)SO_(4) and KMnO_(4) solution the pink colour of KMnO_(4) is dicharged, the mixture may contain

When a salt is heated with dilute H_(2)SO_(4) " and " KMnO_(4) solution, the pink colour of KMnO_(4) is discharged, the salt is :

9.2 grams of N_(2)O_(4(g)) is taken in a closed one litre vessel and heated till the following equilibrium is reached N_(2)O_(4(g))hArr2NO_(2(g)) . At equilibrium, 50% N_(2)O_(4(g)) is dissociated. What is the equilibrium constant (in mol litre^(-1) ) (Molecular weight of N_(2)O_(4) = 92 ) ?

9.2 grams of N_(2)O_(4(g)) is taken in a closed one litre vessel and heated till the following equilibrium is reached N_(2)O_(4(g))hArr2NO_(2(g)) . At equilibrium, 50% N_(2)O_(4(g)) is dissociated. What is the equilibrium constant (in mol litre^(-1) ) (Molecular weight of N_(2)O_(4) = 92 ) ?

VMC MODULES ENGLISH-CHEMICAL EQUILIBRIUM-EFFICIENT
  1. For NH(4)HS(s)hArr NH(3)(g)+H(2)S(g) If K(p)=64atm^(2), equilibrium pr...

    Text Solution

    |

  2. Given equilibrium constants for the following reaction at 1200^(@)C ...

    Text Solution

    |

  3. In a flask colourless N2O4 is in equilibrium with brown coloured NO2. ...

    Text Solution

    |

  4. The following two reactions: i. PCl(5)(g) hArr PCl(3)(g)+Cl(2)(g) ...

    Text Solution

    |

  5. The equilibrium constants for the reaction Br(2)hArr 2Br at 500 K an...

    Text Solution

    |

  6. In reaction: CH(3)COCH(3)(g)hArrCH(3)CH(3)(g)+CO(g), if the initia...

    Text Solution

    |

  7. 2 mole of H(2) and "1 mole of "I(2) are heated in a closed 1 litre ves...

    Text Solution

    |

  8. For the reaction, A(g)+2B(g)hArr2C(g) one mole of A and 1.5 mol of B a...

    Text Solution

    |

  9. If 0.2 mol of H(2)(g) and 2.0 mol of S(s) are mixed in a 1.0 L vessel ...

    Text Solution

    |

  10. The equilibrium K(c)for the reaction SO(2)(g)NO(2)(g)hArrSO(3)(g)+NO(g...

    Text Solution

    |

  11. If in the reaction, N(2)O(4)(g)hArr2NO(2)(g), alpha is the degree of d...

    Text Solution

    |

  12. For the reversible system : X((g))hArrY((g))+Z((g)), a quantity of X w...

    Text Solution

    |

  13. 2 "mole" of PCl(5) were heated in a closed vessel of 2 litre capacity....

    Text Solution

    |

  14. 2 "mole" N(2) and 3 "mole" H(2) gas are allowed to react in a 20 L fla...

    Text Solution

    |

  15. In an aqueous solution of volume 500 ml when the reaction 2Ag^(+)(aq)+...

    Text Solution

    |

  16. The equilibrium constant for the reaction, 2SO(2)(g)+O(2)(g)hArr 2SO...

    Text Solution

    |

  17. Equilibrium constant for the reaction, CaCO(3)(s)hArr CaO(s)+CO(2)(g...

    Text Solution

    |

  18. For the reaction NH(2)COONH(4)(g)hArr 2NH(3)(g)+CO(2)(g) the equilib...

    Text Solution

    |

  19. Given : AhArrB+C, DeltaH=-"10 kcals", the energy of activation of back...

    Text Solution

    |

  20. In preparation of CaO from CaCO(3) using the equilibrium, CaCO(3)(g)hA...

    Text Solution

    |