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The equilibrium constants for the reacti...

The equilibrium constants for the reaction `Br_(2)hArr 2Br`
at 500 K and 700 K are `1xx10^(-10)` and `1xx10^(-5)` respectively. The reaction is:

A

Endothermic

B

Exothermic

C

Fast

D

Slow

Text Solution

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The correct Answer is:
To solve the problem regarding the equilibrium constants for the reaction \( \text{Br}_2 \rightleftharpoons 2\text{Br} \) at different temperatures, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reaction**: The given reaction is \( \text{Br}_2 \rightleftharpoons 2\text{Br} \). This indicates that one mole of bromine gas dissociates into two moles of bromine atoms. 2. **Understand the Given Data**: We have two equilibrium constants: - At 500 K, \( K_c = 1 \times 10^{-10} \) - At 700 K, \( K_c = 1 \times 10^{-5} \) 3. **Analyze the Change in Equilibrium Constant**: As the temperature increases from 500 K to 700 K, the equilibrium constant \( K_c \) increases from \( 1 \times 10^{-10} \) to \( 1 \times 10^{-5} \). This suggests that the reaction favors the formation of products (Br atoms) at higher temperatures. 4. **Determine the Nature of the Reaction**: The increase in \( K_c \) with temperature indicates that the reaction is endothermic. In an endothermic reaction, heat is absorbed, and increasing the temperature shifts the equilibrium towards the products, thereby increasing \( K_c \). 5. **Conclusion**: Since the equilibrium constant increases with temperature, we conclude that the reaction \( \text{Br}_2 \rightleftharpoons 2\text{Br} \) is endothermic. ### Final Answer: The reaction is endothermic.
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