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K(p) and K(p)^(**) are the equilibrium c...

`K_(p) and K_(p)^(**)` are the equilibrium constants of the two reactions, given below
`(1)/(2)N_(2)(g)+(3)/(2)H_(2)(g)hArr NH_(3)(g)`
`N_(2)(g)+3H_(2)(g)hArr 2NH_(3)(g)`
Therefore, `K_(p) and K_(p)^(**)` are related by

A

`K_(p)=(K_(p)^(**))^(2)`

B

`K_(p)=sqrt((K_(p)^(**)))`

C

`K_(p)=2K_(p)^(**)`

D

`K_(p)=K_(p)^(**)`

Text Solution

AI Generated Solution

The correct Answer is:
To find the relationship between the equilibrium constants \( K_p \) and \( K_p^{**} \) for the given reactions, we will analyze each reaction and derive the expressions for their equilibrium constants. ### Step-by-Step Solution: 1. **Identify the Reactions:** - Reaction 1: \(\frac{1}{2} N_2(g) + \frac{3}{2} H_2(g) \rightleftharpoons NH_3(g)\) - Reaction 2: \(N_2(g) + 3 H_2(g) \rightleftharpoons 2 NH_3(g)\) 2. **Write the Expression for \( K_p \) for Reaction 1:** - The equilibrium constant \( K_p \) for Reaction 1 can be expressed as: \[ K_p = \frac{P_{NH_3}}{(P_{N_2})^{1/2} (P_{H_2})^{3/2}} \] 3. **Write the Expression for \( K_p^{**} \) for Reaction 2:** - The equilibrium constant \( K_p^{**} \) for Reaction 2 can be expressed as: \[ K_p^{**} = \frac{(P_{NH_3})^2}{(P_{N_2})(P_{H_2})^3} \] 4. **Relate \( K_p^{**} \) to \( K_p \):** - Notice that \( K_p^{**} \) can be rewritten in terms of \( K_p \): \[ K_p^{**} = \frac{(P_{NH_3})^2}{(P_{N_2})(P_{H_2})^3} \] - If we take the square root of \( K_p^{**} \): \[ \sqrt{K_p^{**}} = \sqrt{\frac{(P_{NH_3})^2}{(P_{N_2})(P_{H_2})^3}} = \frac{P_{NH_3}}{(P_{N_2})^{1/2} (P_{H_2})^{3/2}} \] - This expression matches the expression for \( K_p \) derived from Reaction 1. 5. **Conclusion:** - Therefore, we can conclude that: \[ K_p = \sqrt{K_p^{**}} \] ### Final Relationship: \[ K_p = \sqrt{K_p^{**}} \]
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