Home
Class 12
CHEMISTRY
In the equilibrium constant for N(2)(g) ...

In the equilibrium constant for `N_(2)(g) + O_(2)(g)hArr2NO(g)` is K, the equilibrium constant for `(1)/(2) N_(2)(g) + (1)/(2)O_(2)(g)hArrNO(g)` will be:

A

K

B

`K^(2)`

C

`K^(1//2)`

D

`(K)/(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine the equilibrium constant for the reaction: \[ \frac{1}{2} N_2(g) + \frac{1}{2} O_2(g) \rightleftharpoons NO(g) \] given that the equilibrium constant for the reaction: \[ N_2(g) + O_2(g) \rightleftharpoons 2NO(g) \] is \( K \). ### Step-by-step Solution: 1. **Identify the Original Reaction and Its Equilibrium Constant**: The original reaction is: \[ N_2(g) + O_2(g) \rightleftharpoons 2NO(g) \] The equilibrium constant for this reaction is given as \( K \). 2. **Relate the New Reaction to the Original Reaction**: The new reaction can be obtained by halving the original reaction: \[ \frac{1}{2} N_2(g) + \frac{1}{2} O_2(g) \rightleftharpoons NO(g) \] 3. **Apply the Rule for Changing Reaction Coefficients**: When the coefficients of a balanced equation are multiplied by a factor, the equilibrium constant is raised to the power of that factor. In this case, we have halved the coefficients (multiplied by \( \frac{1}{2} \)): \[ K' = K^{\frac{1}{2}} \] 4. **Write the Final Expression for the New Equilibrium Constant**: Therefore, the equilibrium constant for the new reaction is: \[ K' = K^{\frac{1}{2}} \] ### Final Answer: The equilibrium constant for the reaction \(\frac{1}{2} N_2(g) + \frac{1}{2} O_2(g) \rightleftharpoons NO(g)\) is \( K^{\frac{1}{2}} \). ---
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL EQUILIBRIUM

    VMC MODULES ENGLISH|Exercise Illustration|24 Videos
  • CHEMICAL EQUILIBRIUM

    VMC MODULES ENGLISH|Exercise SOLVED EXAMPLES|20 Videos
  • CHEMICAL EQUILIBRIUM

    VMC MODULES ENGLISH|Exercise EFFICIENT|50 Videos
  • CHEMICAL BONDING-I & II

    VMC MODULES ENGLISH|Exercise JEE Advanced (Archive)|98 Videos
  • CHEMICAL KINETICS

    VMC MODULES ENGLISH|Exercise JEE Advanced (Archive)|52 Videos

Similar Questions

Explore conceptually related problems

If the equilibrium constant for N_(2) (g) + O_(2)(g) hArr 2NO(g) is K , the equilibrium " constant for " 1/2 N_(2) (g) +1/2 O_(2) (g) hArr NO (g) will be

The equilibrium constant for N_(2)(g)+O_(2)(g)hArr2NO "is" K_(1) and that for NO(g)hArr(1)/(2)N_(2)(g)+(1)/(2)O_(2)(g) is K_(2). K_(1) "and" K_(2) will be related as

In the given reaction N_(2)(g)+O_(2)(g) hArr 2NO(g) , equilibrium means that

The equilibrium constant for the reaction N_(2)(g)+3H_(2)(g)hArr2NH_(3)(g) is K and for the reaction (1/2)N_(2)(g)+(3/2)H_(2)(g)hArrNH_(3)(g) is K' K and K' will be related to each other as

The equilibrium constant for the given reaction is 100. N_(2)(g)+2O_(2)(g) hArr 2NO_(2)(g) What is the equilibrium constant for the reaction ? NO_(2)(g) hArr 1//2 N_(2)(g) +O_(2)(g)

For the reaction H_(2)(g)+I_(2)(g)hArr2HI(g) the equilibrium constant K_(p) changes with

For the reaction H_(2)(g)+I_(2)(g)hArr2HI(g) the equilibrium constant K_(p) changes with

Assertion (A) : For N_(2)(g)+3H_(2)(g) hArr 2NH_(3)(g) , the equilibrium constant is K . The for 1/2 N_(2)(g)+3/2H_(2)(g) hArr NH_(3)(g) , the equilibrium constant will be sqrt(K) . Reason (R) : If concentrations are changed to half, the equilibrium constants will be halved.

The equilibrium constant of the reaction, SO_(3)(g) hArr SO_(2)(g)+1//2 O_(2)(g) is 0.15 at 900 K . Calculate the equilibrium constant for 2SO_(2)(g)+O_(2)(g) hArr 2SO_(3)(g)

The equilibrium constant K_(p) for the reaction H_(2)(g)+I_(2)(g) hArr 2HI(g) changes if:

VMC MODULES ENGLISH-CHEMICAL EQUILIBRIUM-IMPECCABLE
  1. In which of the following reaction K(p) gt K(c)

    Text Solution

    |

  2. For the reaction, AB(g)hArr A(g)+B(g), AB" is "33% dissociated at a to...

    Text Solution

    |

  3. In which of the following equilibrium K(c) and K(p) are not equal?

    Text Solution

    |

  4. In the reaction AB(g) hArr A(g) + B(g) at 30^(@)C, k(p) for the dissoc...

    Text Solution

    |

  5. For the reaction C(s) +CO(2)(g) rarr 2CO(g), k(p)=63 atm at 100 K. If ...

    Text Solution

    |

  6. Consider the following gaseous equilibria with equilibrium constant K(...

    Text Solution

    |

  7. Given a gas phase reaction 2A(g)+B(g)hArr C(g)+D(g). Which one of the ...

    Text Solution

    |

  8. alpha-(D) glucose hArr beta (D) glucose, equilibrium constant for this...

    Text Solution

    |

  9. For a chemical reaction of the type AhArrB, K=2.0 and BhArrC, K=0.01. ...

    Text Solution

    |

  10. Which statement is not correct?

    Text Solution

    |

  11. For the reaction, I(2)(aq)hArrI(2)" (oil), Equilibrium constant is K...

    Text Solution

    |

  12. For the reaction, N2(g)+O2(g)hArr2NO(g), the equilibrium constant is...

    Text Solution

    |

  13. For a given exothermic reaction ,KP and Kp' are the equilibrium con...

    Text Solution

    |

  14. For the reversible reaction N(2) (g) +3H(2) (g) hArr 2NH(3) (g) + ...

    Text Solution

    |

  15. if the value of an equilibrium constant for a particular reaction is 1...

    Text Solution

    |

  16. In the equilibrium constant for N(2)(g) + O(2)(g)hArr2NO(g) is K, the ...

    Text Solution

    |

  17. Consider the following liquid-vapour equilibrium Liquid hArr Vapour...

    Text Solution

    |

  18. A 20 litre container at 400 K contains CO(2) (g) at pressure 0.4 atm a...

    Text Solution

    |

  19. Given N(2)(g)+3H(2)(g)hArr2NH(3)(g),K(1) N(2)(g)+O(2)(g)hArr2NO(g)...

    Text Solution

    |

  20. Which one of the following statements is not correct?

    Text Solution

    |