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The number of hydroxyl ions in 100 mL of...

The number of hydroxyl ions in 100 mL of a solution having pH 10 is

A

`1 xx 10^(4)`

B

`3.012 xx 10^(4)`

C

`6.02 xx 10^(18)`

D

`6.023 xx 10^(19)`

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The correct Answer is:
To solve the problem of finding the number of hydroxyl ions (OH⁻) in 100 mL of a solution with a pH of 10, we can follow these steps: ### Step-by-Step Solution: 1. **Understand pH Definition**: The pH of a solution is defined as: \[ \text{pH} = -\log[H^+] \] where \([H^+]\) is the concentration of hydrogen ions in moles per liter. 2. **Calculate [H⁺] from pH**: Given that the pH is 10, we can find the concentration of hydrogen ions: \[ [H^+] = 10^{-\text{pH}} = 10^{-10} \text{ moles per liter} \] 3. **Use the Ion Product of Water**: At 25°C, the product of the concentrations of hydrogen ions and hydroxyl ions is constant: \[ [H^+][OH^-] = 10^{-14} \] We can rearrange this to find \([OH^-]\): \[ [OH^-] = \frac{10^{-14}}{[H^+]} = \frac{10^{-14}}{10^{-10}} = 10^{-4} \text{ moles per liter} \] 4. **Convert to 100 mL**: Since we need the concentration in 100 mL, we convert the concentration from moles per liter to moles per 100 mL: \[ \text{Moles of } OH^- = [OH^-] \times \text{Volume in liters} = 10^{-4} \times \frac{100}{1000} = 10^{-5} \text{ moles} \] 5. **Calculate the Number of Hydroxyl Ions**: To find the number of hydroxyl ions, we use Avogadro's number (\(6.022 \times 10^{23}\) ions per mole): \[ \text{Number of } OH^- \text{ ions} = 10^{-5} \text{ moles} \times 6.022 \times 10^{23} \text{ ions/mole} = 6.022 \times 10^{18} \text{ ions} \] ### Final Answer: The number of hydroxyl ions in 100 mL of a solution having pH 10 is: \[ 6.022 \times 10^{18} \text{ OH}^- \text{ ions} \]
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