The compound obtained by the reaction of diethyl ether with chlorine in the presence of sun light, is-

Options

A. `H_(5) C_(2) - OC_(2) Cl_(5)`
B. `Cl_(5) C_(2) - O - C_(2) Cl_(5) `
​

​
C. `ClCH_(2) CH_(2) - O - CH_(2) CH_(2) Cl`
D. `CH_(3) - underset(Cl)underset(|) (CH) - O - underset(Cl)underset(|) (CH) - CH_(3) `

Answer

To solve the question regarding the compound obtained by the reaction of diethyl ether with chlorine in the presence of sunlight, we can follow these steps:

### Step-by-Step Solution:

1. **Identify the Reactants**:
- The reactant is diethyl ether, which has the molecular formula \( \text{C}_4\text{H}_{10}\text{O} \) or \( \text{CH}_3\text{CH}_2\text{OCH}_2\text{CH}_3 \).

2. **Understand the Reaction Conditions**:
- The reaction occurs in the presence of chlorine (\( \text{Cl}_2 \)) and sunlight. Sunlight provides the energy needed to initiate the reaction.

3. **Recognize the Type of Reaction**:
- This reaction is a free radical substitution reaction. In this type of reaction, chlorine atoms replace hydrogen atoms in the diethyl ether.

4. **Mechanism of the Reaction**:
- The chlorine molecules dissociate into chlorine radicals under the influence of sunlight.
- These chlorine radicals then react with the hydrogen atoms in diethyl ether, replacing them with chlorine atoms.

5. **Determine the Product**:
- Since diethyl ether has 10 hydrogen atoms, all of these can be replaced by chlorine atoms during the reaction.
- The final product will be \( \text{CCl}_3\text{CCl}_2\text{O}\text{CCl}_2\text{CCl}_3 \), which is known as Perchlorodiethyl ether.

6. **Analyze the Options**:
- The options provided in the question need to be evaluated against the product formed.
- The correct answer is the one that matches the structure of Perchlorodiethyl ether, which has all hydrogen atoms replaced by chlorine.

### Final Answer:
The compound obtained by the reaction of diethyl ether with chlorine in the presence of sunlight is **Perchlorodiethyl ether**.

---