Home
Class 12
CHEMISTRY
In the reaction "Phenol" overset(NaO...

In the reaction
`"Phenol" overset(NaOH) to (A) underset(140)overset(CO_(2) + HCl) to (B) ` here B is

A

Benzoic acid

B

Salicylic acid

C

Benzaldehyde

D

Salicyladehyde

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we will follow the steps outlined in the video transcript regarding the reactions of phenol. ### Step 1: Reaction of Phenol with NaOH - **Phenol (C6H5OH)** reacts with **sodium hydroxide (NaOH)**. - This reaction leads to the formation of the sodium salt of phenol, which can be represented as **C6H5O^- Na^+** (sodium phenoxide). **Product A**: Sodium phenoxide (C6H5O^- Na^+) ### Step 2: Reaction of Sodium Phenoxide with CO2 and HCl - The sodium phenoxide then undergoes a reaction with **carbon dioxide (CO2)** in the presence of **hydrochloric acid (HCl)**. - In this reaction, the sodium ion (Na^+) is replaced by a carboxylic acid group (COOH), converting the sodium phenoxide back to a phenolic compound with an additional carboxylic acid group. - The product formed is **salicylic acid (C6H4(OH)COOH)**, which has both a hydroxyl group (OH) and a carboxylic acid group (COOH) on the aromatic ring. **Product B**: Salicylic acid (C6H4(OH)COOH) ### Final Answer Thus, the product B in the reaction is **salicylic acid**. ---
Promotional Banner

Topper's Solved these Questions

  • ALCOHOLS, PHENOLS & ETHERS

    VMC MODULES ENGLISH|Exercise Enable|100 Videos
  • ALCOHOLS, PHENOLS & ETHERS

    VMC MODULES ENGLISH|Exercise Efficient|98 Videos
  • ALCOHOLS, PHENOLS & ETHERS

    VMC MODULES ENGLISH|Exercise IN-CHAPTER EXERCISE - L|10 Videos
  • ALDEHYDES,KETONES & CARBOXYLIC ACIDS

    VMC MODULES ENGLISH|Exercise IN-CHAPTER EXERCISE-M|10 Videos

Similar Questions

Explore conceptually related problems

underset(HCl)overset(NaNO_(2))to product?

Give the structures of A, B and C in the following reactions: C_6H_5NO_2 overset(Fe//HCl) to A underset(273K)overset(NaNO_2 + HCl)to B overset(H_2O //H^(+))toC

Identify the product Z in the following sequence of reactions " phenol" overset(NaOH)rarrX underset(4-7 atm, 410 K)overset(CO_(2))rarrY overset(H_(3)O^(+))rarrZ

In the reaction sequence: CrO_(2)Cl_(2)overset(NaOH) to A overset(dil. H_(2)SO_(4)) to B overset (NaOH) to C overset(AgNO_(3)) to D Identify [A] to [D] .

Product C in the reaction C_(2)H_(5)Br underset(("aqueous"))overset(NaOH)to A overset(Na) to B overset(CH_(3)I)toC will be

VMC MODULES ENGLISH-ALCOHOLS, PHENOLS & ETHERS-Impeccable
  1. In the reaction "Phenol" overset(NaOH) to (A) underset(140)overse...

    Text Solution

    |

  2. The compound that will react most readily with NaOH to from methanol i...

    Text Solution

    |

  3. When ethyl alcohol (C(2) H(5) OH) reacts with thionyl chloride, in t...

    Text Solution

    |

  4. Oil +NaOH(aq) overset(Delta)to Glycerol + Soap Above reaction is ca...

    Text Solution

    |

  5. Which of these is obtained as the product when ethanol is treated with...

    Text Solution

    |

  6. Which of the following product is formed , when ether is exposed to ai...

    Text Solution

    |

  7. Electrophilic substitution in phenol takes place at

    Text Solution

    |

  8. In the sequence of following reactions : CH(3) OH overset(HI)to CH(3) ...

    Text Solution

    |

  9. Following reaction: (CH(3))(3)C-Br +H(2)O rarr (CH(3))(3)C-OH +HBr i...

    Text Solution

    |

  10. The reaction : C(2)H(5)OH + SOCl(2) overset(" Pyridine ")(to) C(2)H(5...

    Text Solution

    |

  11. Glucose to ethyl alcohol in this reaction enzyme is :

    Text Solution

    |

  12. During dehydration of alcohols to alkenes by heating with conc. H(2) S...

    Text Solution

    |

  13. Complete the following reaction

    Text Solution

    |

  14. Propane-1-ol can be prepared from propene

    Text Solution

    |

  15. Cresols are

    Text Solution

    |

  16. Phenol and benzoic acid may be distinguished by their reaction with :

    Text Solution

    |

  17. Which of the following compounds has the highest boiling point ?

    Text Solution

    |

  18. When phenol reacts with phtalic anhydride in presence of H2SO4 and he...

    Text Solution

    |

  19. 4-chloro-3, 5-dimethyl phenol is called

    Text Solution

    |

  20. CH(2) = CH(2) + B(2) H(6) underset(H(2)O(2))overset(NaOH) to Produ...

    Text Solution

    |

  21. Phenol is heated with C Cl(4) and alkaline KOH when salicylic acid is ...

    Text Solution

    |