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In the sequence of following reactions :...

In the sequence of following reactions : `CH_(3) OH overset(HI)to CH_(3) I overset(KCN)to CH_(3) CNoverset("Reduction")toXoverset(HNO_(2))to Y, X ` and Y are respectively

A

`CH_(3) CH_(2) NH_(2) and CH_(3) CH_(2) OH`

B

`CH_(3) CH_(2) NH_(2) and CH_(3) COOH`

C

`CH_(3) CH_(2) OH and CH_(3) CHO`

D

`CH_(3) OCH_(3) and CH_(3) CHO`

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The correct Answer is:
To solve the given sequence of reactions, let's break down each step systematically: ### Step 1: Reaction of Methanol with HI The first reaction involves methanol (CH₃OH) reacting with hydroiodic acid (HI). In this reaction, the hydroxyl group (OH) from methanol is replaced by iodine (I) from HI, resulting in the formation of methyl iodide (CH₃I). **Reaction:** \[ \text{CH}_3\text{OH} + \text{HI} \rightarrow \text{CH}_3\text{I} + \text{H}_2\text{O} \] ### Step 2: Reaction of Methyl Iodide with KCN Next, methyl iodide (CH₃I) reacts with potassium cyanide (KCN). In this reaction, the iodine atom is replaced by the cyanide group (CN), leading to the formation of methyl cyanide (CH₃CN). **Reaction:** \[ \text{CH}_3\text{I} + \text{KCN} \rightarrow \text{CH}_3\text{CN} + \text{KI} \] ### Step 3: Reduction of Methyl Cyanide The next step involves the reduction of methyl cyanide (CH₃CN). During this reduction, the triple bond between carbon and nitrogen in the cyanide group is converted to a single bond, resulting in the formation of ethylamine (CH₃CH₂NH₂). **Reaction:** \[ \text{CH}_3\text{CN} \xrightarrow{\text{Reduction}} \text{CH}_3\text{CH}_2\text{NH}_2 \] ### Step 4: Reaction of Ethylamine with HNO₂ Finally, ethylamine (CH₃CH₂NH₂) reacts with nitrous acid (HNO₂). In this reaction, the amino group (NH₂) is replaced by a hydroxyl group (OH), resulting in the formation of ethanol (CH₃CH₂OH). **Reaction:** \[ \text{CH}_3\text{CH}_2\text{NH}_2 + \text{HNO}_2 \rightarrow \text{CH}_3\text{CH}_2\text{OH} + \text{N}_2 + \text{H}_2\text{O} \] ### Summary of Products - **X (after reduction of CH₃CN)**: Ethylamine (CH₃CH₂NH₂) - **Y (after reaction with HNO₂)**: Ethanol (CH₃CH₂OH) ### Final Answer Thus, the values of X and Y are: - **X = CH₃CH₂NH₂ (Ethylamine)** - **Y = CH₃CH₂OH (Ethanol)** ---
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VMC MODULES ENGLISH-ALCOHOLS, PHENOLS & ETHERS-Enable
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