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When ethyl alcohol (C(2) H(5) OH) reacts...

When ethyl alcohol `(C_(2) H_(5) OH)` reacts with thionyl chloride in the presence of pyridine the product obtained is .

A

`CH_(3) CH_(2) Cl+ HCI`

B

`C_(2) H_(5) Cl+ HCI+SO_(2)`

C

`CH_(3) CH_(2) Cl +H_(2) O + SO_(2)`

D

`CH_(3) CH_(2) Cl + Cl_(2) + SO_(2)`

Text Solution

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The correct Answer is:
To determine the product obtained when ethyl alcohol (C₂H₅OH) reacts with thionyl chloride (SOCl₂) in the presence of pyridine, we can follow these steps: ### Step 1: Identify the Reactants The reactants in this reaction are ethyl alcohol (C₂H₅OH) and thionyl chloride (SOCl₂). Pyridine is used as a base to facilitate the reaction. ### Step 2: Understand the Reaction Mechanism In this reaction, the hydroxyl group (-OH) of ethyl alcohol is substituted by a chlorine atom (Cl). Thionyl chloride acts as a chlorinating agent. ### Step 3: Reaction Process 1. The oxygen atom in the alcohol (C₂H₅OH) is more electronegative and will attract electrons from the sulfur atom in SOCl₂. This leads to the formation of a positively charged sulfur intermediate. 2. The negatively charged chloride ion (Cl⁻) from SOCl₂ will then attack the carbon atom bonded to the hydroxyl group, leading to the substitution of the -OH group with a Cl atom. ### Step 4: Write the Product The product formed from this reaction is ethyl chloride (C₂H₅Cl). Along with this, sulfur dioxide (SO₂) and hydrogen chloride (HCl) are also produced as by-products. ### Step 5: Final Products Thus, the final products of the reaction are: - Ethyl chloride (C₂H₅Cl) - Sulfur dioxide (SO₂) - Hydrogen chloride (HCl) ### Conclusion The product obtained when ethyl alcohol reacts with thionyl chloride in the presence of pyridine is ethyl chloride (C₂H₅Cl). ---
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