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The products formed when diethyl ether i...

The products formed when diethyl ether is reacted with cold HI are `:`

A

`C_(2)H_(5) I`

B

`C_(2) H_(5) I + C_(2) H_(5) OH`

C

`C_(2) H_(5) I + C_(2) H_(6)`

D

`C_(2)H_(5)I+H_(2)O`

Text Solution

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The correct Answer is:
To determine the products formed when diethyl ether reacts with cold hydrogen iodide (HI), we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Structure of Diethyl Ether**: - Diethyl ether has the molecular formula \( \text{C}_4\text{H}_{10}\text{O} \) and can be represented as \( \text{CH}_3\text{CH}_2\text{OCH}_2\text{CH}_3 \). 2. **Understand the Reaction with HI**: - When diethyl ether reacts with cold HI, it dissociates into \( \text{H}^+ \) and \( \text{I}^- \) ions. 3. **Protonation of the Ether**: - The lone pair of electrons on the oxygen atom of diethyl ether attacks the proton (\( \text{H}^+ \)) from hydrogen iodide, leading to the formation of a protonated ether. 4. **Formation of Carbocation**: - The protonation of the ether makes the oxygen positively charged, which weakens the C-O bond. This results in the formation of a carbocation. 5. **Nucleophilic Attack by Iodide Ion**: - The iodide ion (\( \text{I}^- \)), being a good nucleophile, attacks the carbocation formed in the previous step, resulting in the formation of ethyl iodide (\( \text{CH}_3\text{CH}_2\text{I} \)). 6. **Formation of Ethyl Alcohol**: - In addition to ethyl iodide, the reaction also produces ethyl alcohol (\( \text{CH}_3\text{CH}_2\text{OH} \)) as a product from the protonation of one of the ethyl groups. 7. **Final Products**: - Therefore, the final products of the reaction between diethyl ether and cold HI are ethyl iodide and ethyl alcohol. ### Conclusion: The products formed when diethyl ether is reacted with cold HI are ethyl iodide and ethyl alcohol.
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