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The compound A , B and C in the reaction...

The compound A , B and C in the reaction sequence
`CH_(3) - CH_(2) OH overset(PBr_(3))to A overset(Alc. KOH) to B overset(Br_(2))to C` are given by the set :

A

Ethyl bromide, `CH_(3) CH_(2) OH , CH_(3) CHBr_(2)`

B

`C_(2)H_(5) Br, CH -= CH , CH_(2) = CHBr`

C

`C_(2) H_(5) Br, CH_(2) = CH_(2) , CH_(2)Br- CH_(2)Br`

D

`C_(2) H_(5)Br, CH_(3)CH_(2)OH, BrCH_(2)- CH_(2)Br`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we will analyze the reaction sequence step by step to identify the compounds A, B, and C. ### Step 1: Identify Compound A The starting compound is ethanol, which has the structure CH₃-CH₂-OH. When ethanol reacts with phosphorus tribromide (PBr₃), the hydroxyl group (-OH) is replaced by a bromine atom (Br). This reaction results in the formation of ethyl bromide. **Compound A: Ethyl bromide (CH₃-CH₂-Br)** ### Step 2: Identify Compound B Next, ethyl bromide (Compound A) is treated with alcoholic potassium hydroxide (KOH). In this reaction, the bromine atom acts as a good leaving group, and the alcoholic KOH abstracts a proton from the adjacent carbon. This leads to the formation of an alkene through an elimination reaction (dehydrohalogenation). The product formed is ethylene (or ethene). **Compound B: Ethylene (C₂H₄ or CH₂=CH₂)** ### Step 3: Identify Compound C Finally, ethylene (Compound B) reacts with bromine (Br₂). The reaction involves the electrophilic addition of bromine across the double bond of ethylene. This results in the formation of a bromonium ion intermediate, which is then attacked by a bromide ion (Br⁻) leading to the formation of 1,2-dibromoethane. **Compound C: 1,2-Dibromoethane (CH₂Br-CHBr)** ### Summary of Compounds - **Compound A**: Ethyl bromide (CH₃-CH₂-Br) - **Compound B**: Ethylene (C₂H₄ or CH₂=CH₂) - **Compound C**: 1,2-Dibromoethane (CH₂Br-CHBr) ### Final Answer The compounds A, B, and C are: - A: Ethyl bromide (CH₃-CH₂-Br) - B: Ethylene (C₂H₄) - C: 1,2-Dibromoethane (CH₂Br-CHBr)
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