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The ratio of the value of any collogativ...

The ratio of the value of any collogative property for `K_(4)[Fe(CN)_(6)]` solution to that of `Fe_(4)[Fe(CN)_(6)]_(3)`(prussian blue,)solution is nearly

A

1

B

`0.71`

C

1.4

D

Less than 1

Text Solution

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The correct Answer is:
B
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Why K _(3)[Fe(CN)_(6)] is more stable than K_(4)[Fe(CN)_(6)]

Oxidation state of Fe in K_(4)[Fe(CN)_(6)]

In K_(4)[Fe(CN)_(6)],Fe is in the form of

O.N of Fe in K_(4)[Fe(CN)_(6)] is

The compound K_(4)[Fe(CN)_(6)] is called

K_(3)[Fe(CN)_(6)]+FeCl_(2) to Fe_(3)[Fe(CN)_(6)]_(2)darr

What is the expected value of van't Hoff factor for K_(3)[Fe(CN)_(6)] in dilute solution?

Addition of K_(4)[Fe(CN)_(6)] solution to FeCl_(3) solution gives

K_(4)[Fe(CN)_(6)]+2ZnSO_(4) to Zn_(2)[Fe(CN)_(6)]darr+2K_(2)SO_(4)

Write the IUPAC name of Fe_4[Fe(CN)_6]_3 .

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