C(6)H(5) OH and C(6) H(5) COOH show dif...

`C_(6)H_(5) OH and C_(6) H_(5) COOH` show difference in the reaction with

`NaHCO_(3)`

Na metal

NaOH

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Convert C_(6)H_(6) to C_(6)H_(5)D

2C_(6)H_(5)CHO overset(NaOH) to C_(6)H_(5)CH_(2)OH + C_(6)H_(5)COONa The similar reaction can take place with which of the following aldehyde?

Assertion : The major product formed by heating C_(6)H_(5)CH_(2)OC_(2)H_(5) with HI are C_(6)H_(5)CH_(2)I and C_(2)H_(5)OH. Reason : Benzyl cation is more stale than ethyl cation.

A : HCOOH has less pK_(a) than C_(6)H_(5)COOH . R : In C_(6)H_(5)COOH,C_(6)H_(5) - group shows - l effect not +R effect

C_(6)H_(5)COCl+C_(6)H_(5)OH overset(NaOH)toC_(6)H_(5)COOC_(6)H_(5)+HCl This reaction is called :

Consider the two solutions: I: 0.5 M NaCl aqueous solution at 25^(@)C , NaCl is complete ionized. II: 2.0 M C_(6)H_(5)COOH in benzene at 25^(@)C , C_(6)H_(5)COOH dimerizes to the full extent. Which of the following statements(s) is (are) correct?

Out of C_(6)H_(5)CH_(2)Cl and C_(6)H_(5)CHClC_(6)H_(5) , which is more easily hydrolysed by aqueous KOH.

Aldehydes undergo disproportionation reaction in presence of aqueous NaOH. Simultaneou oxidation and reduction of a compound is scientifically called as disproportionation. Aldehydes having no alpha -hydrogen show this rection called Cannizzaro's reaction. Few exception are also there to this represented as : C_(6)H_(5)CHO+C_(6)H_(5)CHO overset(NaOH)underset(Delta)to C_(6)H_(5)COONa+C_(6)H_(5)CH_(2)OH Intramolecular Cannizzaro's reaction is also possible. Answer the following questions : The aldehyde which shows Cannizzaro's reaction is :

IUPAC Name of C_(6)H_(5)COC_(2)H_(5)

Consider the acidity of the carboxylic acids: (a) PhCOOH (b) o-NO_(2) C_(6) H_(4) COOH (c) m-NO_(2) C_(6) H_(4) COOH (d) p-NO_(2) C_(6) H_(4) COOH Which of the following is the strongest acid and why?

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