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Phenol is heated with phthalic anhydride...

Phenol is heated with phthalic anhydride in the presence of conc. `H_(2)SO_(4)`. The product gives pink colour with alkali. The product is

A

Bakelite

B

Phenolphthalein

C

Fluorescene

D

Salicylic acid

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the reaction of phenol with phthalic anhydride in the presence of concentrated sulfuric acid and identify the product formed that gives a pink color with alkali. ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants are phenol (C6H5OH) and phthalic anhydride (C8H4O3). 2. **Understand the Reaction Conditions**: - The reaction takes place in the presence of concentrated sulfuric acid (H2SO4), which acts as a catalyst. 3. **Reaction Mechanism**: - Phthalic anhydride reacts with phenol through an electrophilic aromatic substitution reaction. In this reaction, the anhydride group of phthalic anhydride reacts with the hydroxyl group of phenol. 4. **Formation of the Product**: - The reaction leads to the formation of phenolphthalein, which is a compound derived from the condensation of phenol with phthalic anhydride. 5. **Properties of the Product**: - Phenolphthalein is colorless in acidic solutions and turns pink in basic (alkaline) solutions. This property is crucial for its use as an acid-base indicator. 6. **Conclusion**: - Since the product gives a pink color with alkali, we conclude that the product formed from the reaction of phenol with phthalic anhydride in the presence of concentrated sulfuric acid is **phenolphthalein**. ### Final Answer: The product is **phenolphthalein**. ---
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Knowledge Check

  • When ethylene glycol is heated with oxalic acid in the presence of conc. H_(2)SO_(4) , the product formed is :

    A
    B
    C
    D
  • Phenol reacts with conc. HNO_(3) in the presence of conc. H_(2)SO_(4) to give :

    A
    meta nitrophenol
    B
    ortho nitrophenol
    C
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    D
    picric acid
  • Phenol on heating with NaNO_(2) and a few drops of conc. H_(2)SO_(4) gives :

    A
    p - nitrophenol
    B
    p - nitrosophenol
    C
    o - Nitrophenol
    D
    m - Nitrosophenol
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