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C(6)H(5)COCl+C(6)H(5)OH overset(NaOH)toC...

`C_(6)H_(5)COCl+C_(6)H_(5)OH overset(NaOH)toC_(6)H_(5)COOC_(6)H_(5)+HCl` This reaction is called :

A

Grignard reaction

B

Sandmeyer reaction

C

Etard reaction

D

Schotten-Baumann reaction

Text Solution

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The correct Answer is:
D
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Aldehydes undergo disproportionation reaction in presence of aqueous NaOH. Simultaneou oxidation and reduction of a compound is scientifically called as disproportionation. Aldehydes having no alpha -hydrogen show this rection called Cannizzaro's reaction. Few exception are also there to this represented as : C_(6)H_(5)CHO+C_(6)H_(5)CHO overset(NaOH)underset(Delta)to C_(6)H_(5)COONa+C_(6)H_(5)CH_(2)OH Intramolecular Cannizzaro's reaction is also possible. Answer the following questions : The aldehyde which shows Cannizzaro's reaction is :

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Identify the reagents W, X, Y and Z. C_(6)H_(6) overset(W)to C_(6)H_(5)SO_(3)H overset(X)to C_(6)H_(5)ON a overset(Y)to C_(6)H_(5)OH overset(Z)to C_(6)H_(5)OCOCH_(3)

VMC MODULES ENGLISH-ALCOHOLS, PHENOLS & ETHERS-Enable
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